96283-99-7Relevant articles and documents
Completely stereoselective synthesis of a chiral tetra(tertiary phosphine). Crystal and molecular structure of [OC-6-22(/?,/?)]-(±)-dichloro{l,2-bis[(2-dimethyIphosphinophenyl) methylphosphino]benzene-P,P',P",P'"}cobalt(ni) hexafluorophosphate f
Chatterjee, Swarup,Doyle, Roy,Hockless, David C. R.,Salem, Geoffrey,Willis, Anthony C.
, p. 1829 - 1830 (2000)
Reaction of (±)-(2-chlorophenyl)(2-dimethylphosphinophenyl)methylphosphine with sodium (2-dimethylphosphinophenyl)methylphosphide is completely stereoselective giving (.R,A)-l,2-bis[(2-dimethylphosphinophenyl)methylphosphino]benzene, (R,R)-1; as confirmed