96402-89-0

Basic information

• Product Name: (α,α-dimethyl)benzylhydroxylamine
• Synonyms: (α,α-dimethyl)benzylhydroxylamine
• CAS NO: 96402-89-0
• Molecular Weight: 151.208
• Mol File: 96402-89-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (α,α-dimethyl)benzylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (α,α-dimethyl)benzylhydroxylamine(96402-89-0)
• EPA Substance Registry System: (α,α-dimethyl)benzylhydroxylamine(96402-89-0)

Safety Data

• Hazardous Substances Data: 96402-89-0(Hazardous Substances Data)

Upstream product

• 3457-58-7 2-nitro-2-phenylpropane 
• 1483-73-4 diphenyliodonium bromide 

Relevant articles and documents

Intramolecular Nucleophilic Substitution on Nitrogen A New Heterocyclic Synthesis

A series of 5-(diphenylphosphinyloxyamino)valeric acid esters has been prepared.Their treatment with appropriate bases led to cyclization to proline derivatives.The reaction constitutes the first reported case of intramolecular nucleophilic substitution o

A Fast Procedure for the Reduction of Azides and Nitro Compounds Based on the Reducing Ability of Sn(SR)3-Species

Tin(II) complexes prepared by treatment of SnCl2 or Sn(SR)2 with appropriate amounts of RSH and Et3N appear to be the best reducing agents for azides (to amines) reported so far.Thes tin(II) complexes also reduce primary and secondary aliphatic nitro compounds to oximes, usually within minutes at r.t. or hours in cold, and tertiary aliphaic as well as aromatic nitro compounds to afford the corresponding hydroxylamines.In general, azides react more rapidly than nitro substituents, whereas carbonyl groups, sulphoxides, sulphones, nitriles, and esters are practically unreactive under the same conditions.Some mechanistic details of the reaction of Sn(SPh)3- with azides and nitro compounds have also been elucidated.