96547-44-3

Basic information

• Product Name: 2-Propenoic acid, 3-(2-pyridinyl)-, methyl ester, (Z)-
• CAS NO: 96547-44-3
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.176
• Mol File: 96547-44-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(2-pyridinyl)-, methyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2-pyridinyl)-, methyl ester, (Z)-(96547-44-3)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2-pyridinyl)-, methyl ester, (Z)-(96547-44-3)

Safety Data

• Hazardous Substances Data: 96547-44-3(Hazardous Substances Data)

Upstream product

• 72764-93-3 methyl 3-(pyridin-2-yl)propiolate 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 1121-60-4 pyridine-2-carbaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 5927-18-4 trimethyl phosphonoacetate 

Relevant articles and documents

Copper-Catalyzed Silylcupration of Activated Alkynes

A highly efficient catalytic silylcupration of activated alkynes is reported. Upon reaction with silylboronates and methanol in THF at room temperature in the presence of copper(I) fluoride tris(triphenylphosphine), a range of ynamides and propiolates were found to undergo a smooth silylcupration. This reaction, which tolerates various functional groups, affords a straightforward and efficient entry to the corresponding β-silylenamides and -acrylates, which were formed with high levels of regio- and stereoselectivities.

Stereochemistry of 3-oxo-5-phenylcyclo-pentanecarboxylic acids, XI: Syntheses of stereomeric 3-oxo-5-pyridylcyclopentanecarboxylic acids

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