966-89-2

Basic information

• Product Name: N-(2-phenylcyclohexyl)benzamide
• CAS NO: 966-89-2
• Molecular Formula: C₁₉H₂₁NO
• Molecular Weight: 279.3761
• Mol File: 966-89-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 486.2°C at 760 mmHg
• Flash Point: 295.4°C
• Density: 1.1g/cm³
• Vapor Pressure: 1.33E-09mmHg at 25°C
• Refractive Index: 1.594
• CAS DataBase Reference: N-(2-phenylcyclohexyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-phenylcyclohexyl)benzamide(966-89-2)
• EPA Substance Registry System: N-(2-phenylcyclohexyl)benzamide(966-89-2)

Safety Data

• Hazardous Substances Data: 966-89-2(Hazardous Substances Data)

Upstream product

• 1011-11-6 trans-2-phenylcyclohexylamine 
• 94310-87-9 (+/-)-N-(2c-hydroxy-2t-phenyl-cyclohex-r-yl)-benzamide 
• 1011-11-6 cis-1-amino-2-phenylcyclohexane 
• 98-88-4 benzoyl chloride 
• 94310-87-9 (+/-)-N-(2t-hydroxy-2t-phenyl-cyclohex-r-yl)-benzamide 
• 771-98-2 1-Phenylcyclohexene 
• 5670-71-3 1-nitro-2-phenylcyclohex-1-ene 

Downstream Products

• 108369-78-4 6-phenyl-1,1a,2,3,4,4a-cis-hexahydrophenanthridine 

Relevant articles and documents

Carbon-Skeletal Anionic Rearrangements of Tertiary Benzylic Amines: Geometric and Electronic Requirements for Generating the Spiroazacyclopropane Intermediate

In order to determine the scope and mechanism for the base-promoted rearrangement of tertiary amines, a wide variety of benzylic amines were treated with n-BuLi in THF or TMEDA, n-BuLi-KO-t-Bu mixtures, or KH.The following amines were examined: benzyldimethylamine, benzylmethylphenylamine, benzyldiphenylamine, N-benzylcarbazole, N-benzyl-1,2,3,4-tetrahydrocarbazole, N-benzyl-1,1a,2,3,4,4a-cis-hexahydrocarbazole, N-(2-phenylethyl)carbazole, N-(3-phenylpropyl)carbazole, N-(2-chloroethyl)carbazole, N-benzyl-9,9-dimethyl-9,10-dihydroacridine, N-benzyl-o,o'-iminodibenzyl, 9-(diphenylamino)fluorene, 9-anilino-9-phenylfluorene, 9-(methylphenylamino)fluorene, and diphenyl(diphenylmethyl)amine.In certain cases, ethylation products were obtained from the interaction of intermediate carbanions with ethylene generated by the decomposition of THF.The results are interpreted in terms of intramolecular shifts of aryl groups from nitrogen to benzylic carbon proceeding by way of a bridging aryl transition state or intermediate.