96609-75-5Relevant articles and documents
THERMOLYSIS OF 4-PYRIDYLAZIDES LEADING TO THE SYNTHESIS OF 6H-1,4-DIAZEPINES
Ohba, Yoshihiro,Matsukura, Ikuo,Fukazawa, Yoshimasa,Nishiwaki, Tarozaemon
, p. 287 - 290 (2007/10/02)
Thermolysis of a methanolic solution of 4-pyridylazides (1) at 200 deg C for 8-12 min was found to give unstable but isolable 5-methoxy-6H-1,4-diazepines (4) and (5), along with 32-45percent yield of 5,6-dihydro-6-methoxy-7H-tetrazolodiazepines (6)