96687-45-5

Basic information

• Product Name: Methyl-5-O-benzoyl-2-desoxy-β-D-glycero-pentofuranosid-3-ulose
• Synonyms: Methyl-5-O-benzoyl-2-desoxy-β-D-glycero-pentofuranosid-3-ulose
• CAS NO: 96687-45-5
• Molecular Weight: 250.251
• Mol File: 96687-45-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Methyl-5-O-benzoyl-2-desoxy-β-D-glycero-pentofuranosid-3-ulose(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-5-O-benzoyl-2-desoxy-β-D-glycero-pentofuranosid-3-ulose(96687-45-5)
• EPA Substance Registry System: Methyl-5-O-benzoyl-2-desoxy-β-D-glycero-pentofuranosid-3-ulose(96687-45-5)

Safety Data

• Hazardous Substances Data: 96687-45-5(Hazardous Substances Data)

Upstream product

• 5517-61-3 methyl 3'-O-benzoyl-β-D-apiofuranoside 
• 96622-60-5 Methyl-5-O-benzoyl-2-O-tosyl-β-D-xylofuranosid 
• 98-88-4 benzoyl chloride 
• 51255-17-5 1-O-methyl-2-deoxy-D-ribofuranoside 
• 452-51-7 D-2-deoxyribose 
• 91547-59-0 (2R,3S)-2-(hydroxymethyl)tetrahydrofuran-3-ol 
• 96622-61-6 Methyl-5-O-benzoyl-2-O-tosyl-β-D-erythro-pentofuranosid-3-ulose 
• 121-45-9 phosphorous acid trimethyl ester 
• 144072-00-4 1-methyl-5-O-benzoyl-2-deoxy-β-D-ribofuranoside 
• 96622-64-9 Methyl-2-O-tosyl-β-D-xylofuranosid 

Downstream Products

• 118744-88-0 3'-Deoxy-2',3'-didehydro-3'-methylthymidine 
• 118744-89-1 3'-C-methylidene-2',3'-dideoxy-5-methyluridine 
• 96687-46-6 Methyl-5-O-benzoyl-2-desoxy-α-L-glycero-pentofuranosid-3-ulose 
• 130411-35-7 methyl-5-O-benzoyl-3-C-methyl-2-deoxy-β-D-threo-pentofuranoside 

Relevant articles and documents

Site-selective redox isomerizations of furanosides using a combined arylboronic acid/photoredox catalyst system

In the presence of an arylboronic acid and a hydrogen atom transfer mediator under photoredox conditions, furanoside derivatives undergo site-selective redox isomerizations to 2-keto-3-deoxyfuranosides. Experimental evidence and computational modeling suggest that the transformation takes place by abstraction of the hydrogen atom from the 2-position of the furanoside-derived arylboronic ester, followed by C3-O bond cleavage via spin-center shift. This mechanism is reminiscent of the currently accepted pathway for the formation of 3′-ketodeoxynucleotides by ribonucleotide reductase enzymes.

3'-C-branched 2'-deoxy-5-methyluridines: Synthesis, enzyme inhibition, and antiviral properties

A synthesis scheme for 3'-C-methyl-2'-deoxynucleosides and 3'-C- methylidene-2',3'-dideoxy-5-methyluridine has been proposed with 2- deoxyribose as the starting material. Methyl 5-O-benzoyl-2-deoxyribofuranose was oxidized and the mixture of the 3'-keto d

Studies on the Hydrogenation of Saccharide Enol Phosphates

keto Sugar derivatives with α-acyloxy or α-sulfonyloxy leaving groups lead to formation of enol phosphates by Perkow reaction.On hydrogenation of the isomeric, acyclic enol phosphates 1 and 8 predominantly epimeric deoxy phosphates are obtained.Similarly,