967-35-1

Basic information

• Product Name: N-(4-Methoxyphenyl)-2,4-dinitroaniline
• Synonyms: N-(4-Methoxyphenyl)-2,4-dinitroaniline;2,4-DINITRO-4'-METHOXYDIPHENYLAMINE
• CAS NO: 967-35-1
• Molecular Formula: C₁₃H₁₁N₃O₅
• Molecular Weight: 289.24
• Mol File: 967-35-1.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 444.6°C at 760 mmHg
• Flash Point: 222.7°C
• Appearance: /
• Density: 1.423g/cm³
• Vapor Pressure: 4.21E-08mmHg at 25°C
• Refractive Index: 1.664
• CAS DataBase Reference: N-(4-Methoxyphenyl)-2,4-dinitroaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Methoxyphenyl)-2,4-dinitroaniline(967-35-1)
• EPA Substance Registry System: N-(4-Methoxyphenyl)-2,4-dinitroaniline(967-35-1)

Safety Data

• Hazardous Substances Data: 967-35-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H11N3O5/c1-21-11-5-2-9(3-6-11)14-12-7-4-10(15(17)18)8-13(12)16(19)20/h2-8,14H,1H3

Upstream product

• 104-94-9 4-methoxy-aniline 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 70-34-8 2,4-Dinitrofluorobenzene 
• 120952-16-1 2-(2,4-dinitrophenoxy)-N-ethylpyridinium tetraphenylborate 
• 119-15-3 4-(2,4-dinitroanilino)phenol 
• 74-88-4 methyl iodide 
• 99-65-0 meta-dinitrobenzene 
• 89-02-1 2,4-dinitrobenzenesulfonic acid 

Downstream Products

• 101-64-4 Variamin Blau 
• 36942-33-3 2,6-dichloro-[1,4]benzoquinone-4-(2,4-dinitro-phenylimine) 
• 71491-43-5 amino-2 nitro-4 methoxy-4' diphenylamine 
• 33912-19-5 N₁-(4-methoxyphenyl)benzene-1,2,4-triamine 
• 14823-22-4 1-(4-methoxy-phenyl)-2-methyl-1H-benzoimidazol-5-ylamine 
• 54883-79-3 p-anisyl-1 amino-5 benzotriazole 
• 71491-44-6 1-(4-methoxyphenyl)-5-nitro-1H-benzo[d][1,2,3]triazole 
• 71491-45-7 p-anisyl-1 cyano-5 benzotriazole 
• 18450-21-0 2-Amino-8-methoxy-phenazin 
• 350235-99-3 5-Amino-1-(4-methoxyphenyl)-2-phenyl-1H-benzimidazole 
• 7104-61-2 1-(4-methoxyphenyl)-5-aminobenzimidazole 
• 1366232-44-1 C₂₃H₂₃N₃O 
• 1366232-46-3 C₂₅H₂₇N₃O 
• 1366232-47-4 C₂₅H₂₇N₃O 

Relevant articles and documents

Benzimidazole derivative as well as synthesis method and application thereof

The invention discloses a benzimidazole derivative as well as a synthesis method and application thereof, and relates to the technical field of antiviral therapeutic drugs. According to the benzimidazole derivative as well as the synthesis method and appl

Synthesis of o-Nitroarylamines via Ipso Nucleophilic Substitution of Sulfonic Acids

A mild, efficient, and eco-friendly method for the synthesis of o-nitroarylamine from o-nitroaryl sulfonic acid via ipso nucleophilic aryl substitution by amine is described. The products have been obtained with good yields at room temperature without the assistance of any metal, activating agent, or toxic oxidant. This method is useful for racemization-free synthesis of N-aryl amino acid esters.

“Zero VOC” Synthetic Strategy – Aromatic Amination Reactions in Deep Eutectic Solvents

Rising concern for environment hazards resulting from the use of volatile organic compounds (VOCs) is prompting many chemists to use “green” solvents like water, polyethylene glycol, ionic liquids and deep eutectic solvents (DES). With a few notable exceptions, many of these processes still need to use volatile organic solvents for the workup and isolation of products. In the present report, we demonstrate a “zero VOC” protocol which eliminates the need to use organic solvents for any stage of the reaction. As a proof of concept, nucleophilic aromatic substitution reactions of 1-halo-2,4-dinitrobenzene with secondary amines were carried out in deep eutectic solvents. The reaction workup involved the addition of water for separating the product from the DES. Evaporation of water led to recovery of the DES, which exhibited good recyclability. The reaction in deep eutectic solvents was much faster than that in many other solvents, as confirmed by the kinetic studies. An attempt was made to elucidate the origin of this rate enhancement based on analysis activation parameters and correlation with the polarity parameters. The results show that use of deep eutectic solvents can take chemists a step closer towards the “zero VOC” synthetic strategy.