96708-13-3

Basic information

• Product Name: (+/-)-cis-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾
• CAS NO: 96708-13-3
• Molecular Weight: 324.422
• Mol File: 96708-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-cis-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-cis-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾(96708-13-3)
• EPA Substance Registry System: (+/-)-cis-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾(96708-13-3)

Safety Data

• Hazardous Substances Data: 96708-13-3(Hazardous Substances Data)

Upstream product

• 451-40-1 phenyl benzyl ketone 
• 1896-62-4 (E)-benzalacetone 
• 10285-13-9 (+/-)-erythro-1.2.3-triphenyl-hexanedione-(1.5) 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 620-80-4 ethyl 2-benzylidene acetoacetate 
• 645-49-8 cis-stilben 
• 61764-76-9 1,2,3-triphenylhexane-1,5-dione 

Downstream Products

• 1460-62-4 2,3,4-Triphenyl-cyclohexen-1 
• 10462-08-5 (+/-)-trans-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾-oxime 
• 10462-08-5 (+/-)-cis-1.2.3-triphenyl-cyclohexen-⁽³⁾-one-⁽⁵⁾-oxime 
• 1165-14-6 1,2,3-triphenylbenzene 
• 10462-08-5 3,4,5-triphenyl-cyclohex-2-enone oxime 

Relevant articles and documents

Photocycloaddition of Some Difluoro(aminoenonato)boron Complexes with Arylalkenes

The photocycloaddition of some difluoro [(methylamino- κ N)alkenonato-κO]boron complexes 1 with arylalkenes 2 is discussed. The resulting [2 + 2] photoaddition gave the cyclobutane and azetidine derivatives (Schemes 1, 3, and 5). Rearrangements of the cyclobutane gave 1,5-diketones derivatives (Schemes 2, 4, and 5). The yields of the photoadducts were governed by the reduction and oxidation potentials. Furthermore, the configurations of the products established high regio- and stereoselectivity, suggesting the presence of a singlet exciplex. The reactivity and the stereochemistry were rationalized by means of FMO (frontier molecular orbital) calculations.