96802-31-2

Basic information

• Product Name: 1-phenylsulfanyl-4-p-tolylsulfanyl-benzene
• Synonyms: 1-phenylsulfanyl-4-p-tolylsulfanyl-benzene
• CAS NO: 96802-31-2
• Molecular Weight: 308.468
• Mol File: 96802-31-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenylsulfanyl-4-p-tolylsulfanyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylsulfanyl-4-p-tolylsulfanyl-benzene(96802-31-2)
• EPA Substance Registry System: 1-phenylsulfanyl-4-p-tolylsulfanyl-benzene(96802-31-2)

Safety Data

• Hazardous Substances Data: 96802-31-2(Hazardous Substances Data)

Upstream product

• 623-13-2 4-methylphenyl methylsulfide 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 65662-88-6 phenyl(4-bromophenyl)sulfide 
• 106-45-6 para-thiocresol 

Relevant articles and documents

Regioselective C-H Sulfanylation of Aryl Sulfoxides by Means of Pummerer-Type Activation

A regioselective C-H sulfanylation of aryl sulfoxides with alkyl aryl sulfides in the presence of acid anhydride was developed, which resulted in the formation of 1,4-disulfanylarenes after dealkylation of initially formed sulfonium salts. The reaction began with Pummerer-type activation of aryl sulfoxides followed by nucleophilic attack of alkyl aryl sulfides. The nucleophilic attack occurred exclusively at the para positions, or at specific positions in case the para position was not available, under perfect control by the dominating sulfoxide directors regardless of any other substituents. The initially formed aryl sulfonium salts were isolable and usefully served as aryl halide surrogates for palladium-catalyzed arylation with sodium tetraarylborates.

"β-cis-SAr effect" on decarbonylation from α,β-unsaturated acyl and aroyl complexes

Lone pair of heteroatom located at the β-cis position in α,β-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions. The Royal Society of Chemistry 2006.