96844-07-4

Basic information

• Product Name: Benzene, 1-methyl-4-[(S)-2-propenylsulfinyl]-
• CAS NO: 96844-07-4
• Molecular Formula: C10H12OS
• Molecular Weight: 180.271
• Mol File: 96844-07-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(S)-2-propenylsulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(S)-2-propenylsulfinyl]-(96844-07-4)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(S)-2-propenylsulfinyl]-(96844-07-4)

Safety Data

• Hazardous Substances Data: 96844-07-4(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 32018-21-6 2-[(4-methylphenyl)sulfanyl]ethyl phenyl sulfone 
• 556-56-9 allyl iodid 
• 1308833-65-9 1-methyl-4-[(2-(phenylsulfonyl)ethyl)sulfinyl]benzene 
• 1516-28-5 allyl (p-tolyl)sulfide 

Downstream Products

• 102734-14-5 (-)-(S)-7,7-dimethylbicyclo<3.3.0>-2-octen-3-one 

Relevant articles and documents

Organocatalytic asymmetric synthesis of sulfoxides from sulfenic acid anions mediated by a cinchona -derived phase-transfer reagent

Preliminary results concerning a conceptually novel route to chiral sulfoxides based on the asymmetric alkylation of sulfenate salts with alkyl halides mediated by a chiral phase-transfer catalyst are described. As a representative example, o-anisyl methyl sulfoxide was produced in 96% yield and with an enantiomeric excess of 58% using commercial cinchonidinium derivative 2a.

ASYMMETRIC SYNTHESIS OF CHIRAL SULFOXIDES VIA MICROBIAL OXIDATION OF SULFIDES

Incubation of alkyl aryl and allyl aryl sulfides with growing cells of Corynebacterium equi IFO 3730 gave the corresponding optically active sulfoxides with high enantiomeric excess.