96881-37-7

Basic information

• Product Name: 1H-Imidazo[1,2-a]purine-7-carboxaldehyde, 4,9-dihydro-4,6-dimethyl-9-oxo-1-(phenylmethyl)-
• CAS NO: 96881-37-7
• Molecular Formula: C17H15N5O2
• Molecular Weight: 321.338
• Mol File: 96881-37-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1H-Imidazo[1,2-a]purine-7-carboxaldehyde, 4,9-dihydro-4,6-dimethyl-9-oxo-1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Imidazo[1,2-a]purine-7-carboxaldehyde, 4,9-dihydro-4,6-dimethyl-9-oxo-1-(phenylmethyl)-(96881-37-7)
• EPA Substance Registry System: 1H-Imidazo[1,2-a]purine-7-carboxaldehyde, 4,9-dihydro-4,6-dimethyl-9-oxo-1-(phenylmethyl)-(96881-37-7)

Safety Data

• Hazardous Substances Data: 96881-37-7(Hazardous Substances Data)

Upstream product

• 124910-11-8 (E)-1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one 
• 65120-81-2 1-benzyl-4,6-dimethyl-1,4-dihydro-imidazo[1,2-a]purin-9-one 
• 68-12-2 N,N-dimethyl-formamide 
• 79-37-8 oxalyl dichloride 
• 110691-69-5 (R^*,R^*)-1-benzyl-1,4-dihydro-7-(1,2-dihydroxy-3-methylbutyl)-4,6-dimethyl-9H-imidazo-<1,2-a>purin-9-one 
• 65120-78-7 7-benzyl-3-methylguanine 
• 100-39-0 benzyl bromide 
• 2958-98-7 3-methylguanine 
• 96881-38-8 1-benzyl-1,4-dihydro-7-hydroxymethyl-4,6-dimethyl-9H-imidazo<1,2-a>purin-9-one 
• 124927-18-0 <(1-benzyl-4,9-dihydro-4,6-dimethyl-9-oxo-1H-imidazo<1,2-a>purin-7-yl)methyl>triphenylphosphonium bromide 

Downstream Products

• 63103-76-4 diphenyl 2-methylpropyl phosphine oxide 
• 124910-08-3 (E)-1-benzyl-1,4-dihydro-4,7-dimethyl-6-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one 
• 124910-10-7 (Z)-1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one 
• 124910-11-8 (E)-1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one 
• 96854-31-8 -4-<1-Benzyl-4,9-dihydro-4,6-dimethyl-9-oxo-1H-imidazo<1,2-a>purin-7-yl>-2-<(methoxycarbonyl)amino>-3-butenoic Acid Methyl Ester 
• 35693-91-5 wybutine 
• 110691-69-5 (R*,S*)-1-benzyl-1,4-dihydro-7-(1,2-dihydroxy-3-methylbutyl)-4,6-dimethyl-9H-imidazo<1,2-a>purin-9-one 
• 110691-72-0 1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methylbutyl)-9H-imidazo<1,2-a>purin-9-one 
• 122775-74-0 bis(1-benzyl-4,9-dihydro-4,6-dimethyl-9-oxo-1H-imidazo<1,2-a>purin-7-yl)methane 
• 122775-60-4 1-benzyl-1,4-dihydro-4,6,7-trimethyl-9H-imidazo<1,2-a>purin-9-one 
• 214117-24-5 (+/-)-1-benzyl-α-<(methoxycarbonyl)amino>-β-oxo-4,6-dimethyl-9-oxo-4,9-dihydro-1H-imidazo<1,2-a>purine-7-butanoic acid methyl ester 
• 70363-52-9 (R*,S*)-β-hydroxy-α-<(methoxycarbonyl)amino>-4,6-dimethyl-9-oxo-4,9-dihydro-1H-imidazo<1,2-a>purine-7-butanoic acid methyl ester 
• 70363-52-9 (R*,R*)-β-hydroxy-α-<(methoxycarbonyl)amino>-4,6-dimethyl-9-oxo-4,9-dihydro-1H-imidazo<1,2-a>purine-7-butanoic acid methyl ester 
• 110658-45-2 <4R-<4α(S^*),5β>>-5-<1-benzyl-4,9-dihydro-4,6-dimethyl-9-oxo-1H-imidazo<1,2-a>purin-7-yl>-α-<(methoxycarbonyl)amino>-2-oxo-1,3-dioxolane-4-acetic acid methyl ester 

Relevant articles and documents

Synthesis of β-hydroxywybutines, the most probable alternatives for the hypermodified base of rat liver phenylalanine transfer ribonucleic acid

Deoxygenation of the 1,2-glycol (±)-5 was achieved at the position adjacent to the heterocycle through the cyclic carbonate (±)-14, providing the monohydroxy compound 6. This new method of regioselective deoxygenation was employed for the first synthesis

Studies towards the synthesis of the fluorescent bases of phenylalanine transfer ribonucleic acids: synthesis of 7-methylwye isolated from extremely thermophilic archaebacteria.

Acid- or base-catalyzed acylation of 1-benzylwye (7) provided the 7-substituted derivatives 9, 10, and 11 in poor yields. Although the reactions of lithiated 7 with electrophiles gave the 2-substituted derivatives 14, 15, 17, 20, 21, and 22, lithiation of

SYNTHESIS OF (S)-(-)-WYBUTINE, THE FLUORESCENT MINOR BASE FROM YEAST PHENYLALANINE TRANSFER RIBONUCLEIC ACIDS

The Wittig reaction of 1-benzyl-7-formylwye (12) with (R)-ethyl>triphenylphosphonium chlorid (8) followed by successive methylation and reduction gave (-)-wybutine .