96921-50-5

Basic information

• Product Name: 4-Benzenesulfonyl-4-methyl-hex-5-enoic acid methyl ester
• Synonyms: 4-Benzenesulfonyl-4-methyl-hex-5-enoic acid methyl ester
• CAS NO: 96921-50-5
• Molecular Weight: 282.361
• Mol File: 96921-50-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-Benzenesulfonyl-4-methyl-hex-5-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Benzenesulfonyl-4-methyl-hex-5-enoic acid methyl ester(96921-50-5)
• EPA Substance Registry System: 4-Benzenesulfonyl-4-methyl-hex-5-enoic acid methyl ester(96921-50-5)

Safety Data

• Hazardous Substances Data: 96921-50-5(Hazardous Substances Data)

Upstream product

• 873-55-2 sodium benzenesulfonate 
• 81769-17-7 methyl 4-methyl-4-nitro-5-hexenoate 
• 25932-11-0 benzenesulfinic acid sodium dihydrate 

Relevant articles and documents

Regioselective Preparation of Allylic Sulfones by Palladium-Catalyzed Reactions of Allylic Nitro Compounds with Sodium Benzenesulfinate

Treatment of allylic nitro compounds with sodium benzenesulfinate in the presence of 5 molpercent of Pd(PPh3)4 in N,N-dimethylformamide (DMF) at 20-70 deg C for 1-10 h resulted in the formation of allylic sulfones with predominance of kinetically controll

Direct Conversion of Allylic Nitro Compounds into Allyl Sulphides and Allyl Sulphones

Allylic nitro compounds are directly converted into allyl sulphides or allyl sulphones with high regioselectivity on treatment with sodium benzenethiolate alone or with sodium benzenesulphinate in the presence of a catalytic amount of Pd(PPh3)4.