96937-98-3Relevant articles and documents
Alternative approach to the synthesis of optically active β-keto sulfoxides by furylhydroperoxides enantioselective oxidations
Lattanzi, Alessandra,Bonadies, Francesco,Schiavo, Annamaria,Scettri, Arrigo
, p. 2619 - 2625 (2007/10/03)
Enantiomerically enriched β-keto sulfoxides are obtainable by an alternative method to the classical reaction of the enantiomerically pure α- sulfinyl anion with esters or by Anderson's synthesis, through Sharpless modified kinetic resolution of racemic β-keto sulfoxides. High e.e.s are achieved by combining asymmetric oxidation and kinetic resolution using furylhydroperoxides as oxidants.