96998-17-3Relevant articles and documents
Cobalt(II) Chloride. Aluminium Promoted Allylation of Aldehydes with Allylic Halides
Khan, Rahat H.,Prasada Rao, Turga S.R.
, p. 202 - 203 (1998)
In the presence of cobalt(II) chloride-metallic aluminium, allylic halides react with aldehydes at room temperature in tetrahydrofuran-water to afford the corresponding alcohols in high yields.
Study on the coupling of acyclic esters with alkenes - The synthesis of 2-(2-hydroxyalkyl)cyclopropanols via cascade cyclization using allylsamarium bromide
Tu, Yawei,Zhou, Liejin,Yin, Ruifeng,Lv, Xin,Flowers Ii, Robert A.,Choquette, Kimberly A.,Liu, Huili,Niu, Qingsheng,Wang, Xiaoxia
supporting information, p. 11026 - 11028 (2013/01/15)
The radical cyclization between aliphatic acyclic esters and alkenes was achieved unprecedentedly in the presence of allylsamarium bromide with HMPA and H2O as additives. The cascade radical cyclization-ring-opening- anionic cyclization allowed facile and efficient access to 2-(2-hydroxyalkyl) cyclopropanols from readily available materials.
Novel carbonyl allylation mediated by SnCl2/TiCl3 in water
Tan, Xiang-Hui,Shen, Bo,Beng, Wei,Zhao, Hui,Liu, Lei,Guo, Qing-Xiang
, p. 1833 - 1835 (2007/10/03)
(Matrix presented) Under the Lewis acid catalysis offered by TiCl 3, SnCl2 can efficiently mediate the aqueous Barbier reactions between aldehydes and allyl chloride or bromide.
