97033-27-7

Basic information

• Product Name: 2,2'-DICHLORO-[3,3']-BIPYRIDINE
• Synonyms: 2,2'-DICHLORO-[3,3']-BIPYRIDINE
• CAS NO: 97033-27-7
• Molecular Formula: C10H6Cl2N2
• Molecular Weight: 225.07404
• Mol File: 97033-27-7.mol
• Article Data: 3

Chemical Properties

• Melting Point: 116-122℃
• Boiling Point: 333.3°Cat760mmHg
• Flash Point: 185.6°C
• Appearance: /
• Density: 1.363g/cm³
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2,2'-DICHLORO-[3,3']-BIPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-DICHLORO-[3,3']-BIPYRIDINE(97033-27-7)
• EPA Substance Registry System: 2,2'-DICHLORO-[3,3']-BIPYRIDINE(97033-27-7)

Safety Data

• Hazardous Substances Data: 97033-27-7(Hazardous Substances Data)

Usage

General Description

2,2'-Dichloro-[3,3']-bipyridine is a chemical compound with the molecular formula C10H6Cl2N2. It is a bipyridine derivative with two chlorine atoms attached to the 2 and 2' positions of the aromatic ring. 2,2'-DICHLORO-[3,3']-BIPYRIDINE is commonly used as a ligand in coordination chemistry and is known for its ability to form stable complexes with various metal ions. It is widely utilized in the synthesis of coordination polymers, metal-organic frameworks, and other complex materials. Additionally, 2,2'-dichloro-[3,3']-bipyridine has been studied for its potential applications in catalysis and as a building block in the development of novel functional materials.

Upstream product

• 97033-22-2 2,2'-dinitro-3,3'-bipyridine 
• 77200-37-4 <3,3'-bipyridine>-2,2'-diamine 
• 54231-33-3 3-bromo-2-nitropyridine 
• 109-09-1 2-chloropyridine 

Relevant articles and documents

Extending motifs in lithiocuprate chemistry: Unexpected structural diversity in thiocyanate complexes

The new area of lithio(thiocyanato)cuprates has been developed. Using inexpensive, stable and safe CuSCN for their preparation, these complexes revealed Lipshutz-type dimeric motifs with solvent-dependent point group identities; planar, boat-shaped and chair shaped conformers are seen in the solid state. In solution, both Lipshutz-type and Gilman structures are clearly seen. Since the advent in 2007 of directed ortho cupration, effort has gone into understanding the structure-reactivity effects of amide ligand variation in and alkali metal salt abstraction from Lipshutz-type cuprates such as (TMP)2Cu(CN)Li2(THF) 1 (TMP = 2,2,6,6-tetramethylpiperidide). The replacement of CN- with SCN- is investigated presently as a means of improving the safety of lithium cuprates. The synthesis and solid state structural characterization of reference cuprate (TMP)2Cu(CN)Li2(THP) 8 (THP = tetrahydropyran) precedes that of the thiocyanate series (TMP)2Cu(SCN)Li2(L) (L = OEt29, THF 10, THP 11). For each of 9-11, preformed TMPLi was combined with CuSCN (2 : 1) in the presence of sub-stoichiometric Lewis base (0.5 eq. wrt Li). The avoidance of Lewis basic solvents incurs formation of the unsolvated Gilman cuprate (TMP)2CuLi 12, whilst multidimensional NMR spectroscopy has evidenced the abstraction of LiSCN from 9-11 in hydrocarbon solution and the in situ formation of Gilman reagents. The synthetic utility of 10 is established in the selective deprotometalation of chloropyridine substrates, including effecting transition metal-free homocoupling in 51-69% yield.

Bipyridines. Part XV. A Novel Convenient Synthesis of Some 3,3'-Bipyridine Derivatives

A new, convenient synthesis of 2,2'-dinitro-(10), 4,4'-dinitro-(11), 1,1'-dioxo-4,4'-dinitro- (12) and 2,2'-dioxo- (13) -3,3'-bipyridines by aplication of the Ullmann reaction is reported.The possibility of the nitro-groups substitution by such nucleophil