97067-47-5Relevant articles and documents
SYNTHESIS OF PRIMARY-DITERTIARY ENYNETRIOLS AND THEIR MONOETHERS AND THEIR HYDROGENATION
Sabirov, S. S.,Faizilov, I. U.,Isobaev, M. D.
, p. 883 - 887 (2007/10/02)
Primary-ditertiary cis- and trans-enynetriols and their monoethers were obtained by the condensation of enynyl alcohol with the hydroxy ketones and keto ethers under the conditions of the Favorskii reaction in liquid ammonia.When heated in the presence of alkaline agents, they dissociate into the initial reagents.The cis- and trans-enynetriols and their monoethers are hydrogenated at a platinum catalyst at various rates to the saturated analogs.