97222-05-4

Basic information

• Product Name: heptyl 4-chlorobenzoate
• Synonyms: heptyl 4-chlorobenzoate
• CAS NO: 97222-05-4
• Molecular Weight: 254.757
• Mol File: 97222-05-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: heptyl 4-chlorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: heptyl 4-chlorobenzoate(97222-05-4)
• EPA Substance Registry System: heptyl 4-chlorobenzoate(97222-05-4)

Safety Data

• Hazardous Substances Data: 97222-05-4(Hazardous Substances Data)

Upstream product

• 629-04-9 1-Bromoheptane 
• 104-88-1 4-chlorobenzaldehyde 
• 24300-70-7 3,4-dimethylthiazolinium iodide 
• 111-70-6 n-heptan1ol 
• 74-11-3 para-chlorobenzoic acid 
• 96-09-3 styrene oxide 
• 106-39-8 bromochlorobenzene 

Relevant articles and documents

Pd/C-Catalyzed Carbonylative Esterification of Aryl Halides with Alcohols by Using Oxiranes as CO Sources

A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway. Intramolecular versions of this process serve as methods for the synthesis of lactones and phthalimides. CO gas free! A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway (see scheme).

NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

A NHCs-mediated benzoates formation was developed by treatment of aromatic aldehydes with alkyl halides in the presence of oxygen. Corresponding benzoate derivatives were obtained in high yields up to 99%. The reaction mechanism was also discussed and a NHCs-mediated O-alkylation and subsequent oxidation process was proposed.