97371-32-9

Basic information

• Product Name: N⁵-benzyloxycarbonyl-DL-ornithine methyl ester; hydrochloride
• Synonyms: N⁵-benzyloxycarbonyl-DL-ornithine methyl ester; hydrochloride
• CAS NO: 97371-32-9
• Molecular Weight: 316.785
• Mol File: 97371-32-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N⁵-benzyloxycarbonyl-DL-ornithine methyl ester; hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: N⁵-benzyloxycarbonyl-DL-ornithine methyl ester; hydrochloride(97371-32-9)
• EPA Substance Registry System: N⁵-benzyloxycarbonyl-DL-ornithine methyl ester; hydrochloride(97371-32-9)

Safety Data

• Hazardous Substances Data: 97371-32-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 70671-51-1 N⁵-benzyloxycarbonyl-DL-ornithine 

Relevant articles and documents

Triple role of phenylselenonyl group enabled a one-pot synthesis of 1,3-oxazinan-2-ones from α-isocyanoacetates, phenyl vinyl selenones, and water

Reaction of α-substituted α-isocyanoacetates with phenyl vinyl selenones in the presence of a catalytic amount of base (DBU or Et3N, 0.05-0.1 equiv) followed by addition of p-toluenesulfonic acid (PTSA, 0.1-0.2 equiv) afforded 4,4,5-trisubstituted 1,3-oxazinan-2-ones in good to excellent yields. Enantiomerically enriched heterocycles can also be prepared using a Cinchona alkaloid-derived bifunctional organocatalyst for the Michael addition step. The phenylselenonyl group served as an activator for the Michael addition, a leaving group and a latent oxidant in this integrated reaction sequence.