97385-59-6

Basic information

• Product Name: tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)cobalt hexafluorophosphate
• CAS NO: 97385-59-6
• Molecular Weight: 941.775
• Mol File: 97385-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)cobalt hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)cobalt hexafluorophosphate(97385-59-6)
• EPA Substance Registry System: tris[(2-hydroxyethyl)isocyanide]bis(triphenylphosphane)cobalt hexafluorophosphate(97385-59-6)

Safety Data

• Hazardous Substances Data: 97385-59-6(Hazardous Substances Data)

Upstream product

• 14126-40-0 bis(triphenylphosphine)dichlorocobalt(II) 
• 32835-59-9 (2-Hydroxyethyl)isocyanid 

Relevant articles and documents

Metal Complexes of Functional Isocyanides, X. On Hydroxyalkyl Isocyanides and Their Stabilization in Metal Complexes

The hydroxyalkyl isocyanides CNnOH (n = 2 (1a), 3 (1d), 5 (1e)), CNCH(Et)CH2OH (1b), and CNCH2CH(Me)OH (1c) have been synthesized from N-(hydroxyalkyl)formamides by dehydration with equimolar amounts of phosgene in the presence of triethylamine, spectroscopically (IR, 1H, 13C NMR) characterized and introduced into metal complexes, which stabilize 1a - e in the open chain form.The OH group of coordinated hydroxy isocyanides can be esterified or substituted for Cl.Conversely, hydrolysis of CNCH2OC(O)Ph in a series of newly prepared metal complexes of this ligandto give isocyanohydrin (CNCH2OH) complexes has not been accomplished.