97492-32-5

Basic information

• Product Name: Benzamide, 3-methoxy-N-(3-methoxyphenyl)-
• CAS NO: 97492-32-5
• Molecular Formula: C15H15NO3
• Molecular Weight: 257.289
• Mol File: 97492-32-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzamide, 3-methoxy-N-(3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 3-methoxy-N-(3-methoxyphenyl)-(97492-32-5)
• EPA Substance Registry System: Benzamide, 3-methoxy-N-(3-methoxyphenyl)-(97492-32-5)

Safety Data

• Hazardous Substances Data: 97492-32-5(Hazardous Substances Data)

Upstream product

• 108715-03-3 3,3'-dimethoxy-benzophenone oxime 
• 536-90-3 m-Anisidine 
• 1711-05-3 m-anisoyl chloride 
• 766-85-8 3-methoxy-1-iodobenzene 
• 144-62-7 oxalic acid 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

Supported-Pd catalyzed tandem approach for N-arylbenzamides synthesis

Aryl iodides as dual arylating agent for C-terminal from oxalic acid [(CO2H)2] and N-terminal from sodium azide (NaN3) for N-aryl benzamides (Ar-CO-NH-Ar) synthesis is a rare invention which has been attempted successfully under this study. A single step tandem approach for the synthesis of N-aryl benzamides has been developed through bifunctional transformation of aryl iodides with in-situ CO from (CO2H)2 and NaN3 following two different pathways of carbonylation and azidation. The polystyrene supported palladium (Pd@PS) catalyst was found to be well compatible to perform the domino-reaction in a double layer vial (DLV) system under base, ligand and additive-free conditions. Moreover, the same approach was further extended with aryl azides for unsymmetric N-aryl benzamides (Ar-CO-NH-Ar') synthesis. Furthermore, the DFT studies were also performed to support the proposed mechanism.

Convenient palladium-catalyzed aminocarbonylation of anilines to N-arylbenzamides

The first one-pot diazotization/aminocarbonylation reaction of anilines to benzamides has been developed. In the presence of commercially available palladium acetate/P(o-Tolyl)3 as the catalyst system without base at low temperature (50°C) a variety of amides were synthesized in moderate to good yields.