97499-79-1

Basic information

• Product Name: octyl vinyl adipate
• Synonyms: octyl vinyl adipate
• CAS NO: 97499-79-1
• Molecular Weight: 284.396
• Mol File: 97499-79-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: octyl vinyl adipate(CAS DataBase Reference)
• NIST Chemistry Reference: octyl vinyl adipate(97499-79-1)
• EPA Substance Registry System: octyl vinyl adipate(97499-79-1)

Safety Data

• Hazardous Substances Data: 97499-79-1(Hazardous Substances Data)

Upstream product

• 111-87-5 octanol 
• 4074-90-2 divinyl adipate 

Relevant articles and documents

Mono-substitution of symmetric diesters: Selectivity of: Mycobacterium smegmatis acyltransferase variants

A method for selectively reacting one, out of two identical carboxylic esters in a symmetric diester has been developed. An esterase from Mycobacterium smegmatis (MsAcT) has a restricted active site resulting in a narrow acyl donor specificity. This constraint was used to develop a selective synthesis route from divinyl adipate (a symmetric diester) towards mixed vinyl adipate esters. To find a suitable catalyst, the wild type (wt) MsAcT and two MsAcT variants: A single point mutant (L12A) and a double point mutant (T93A/F154A), were immobilized and studied under solvent-free conditions. Out of the tested catalysts, MsAcT L12A was the most selective for mono-Transesterification of divinyl adipate. When divinyl adipate was reacted with 1.5 equivalents of a hydroxyl vinyl ether full conversion of DVA was observed yielding over 95% mixed diester. Furthermore, the limitations for longer dicarboxylic esters were studied, showing that MsAcT T93A/F154A tolerated up to at least dimethyl sebacate.