97594-98-4Relevant articles and documents
Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters
Cao, Xu,Lu, Kai,Ma, Mengtao,Wang, Weifan,Xue, Fei,Yao, Weiwei
, p. 2776 - 2780 (2020)
A low-valent magnesium(i) complex [(XylNacnac)Mg]2 was employed as a highly efficient precatalyst for the hydroboration of a variety of cyclic and linear organic carbonates, polycarbonates, CO2 and esters with HBpin under mild conditions. The resultant boronates can be used for the preparation of the corresponding value-added diols, triols or alcohols through hydrolysis.