97597-31-4

Basic information

• Product Name: rac-2-cyclohexylidene-1-phenylethan-1-ol
• Synonyms: rac-2-cyclohexylidene-1-phenylethan-1-ol
• CAS NO: 97597-31-4
• Molecular Weight: 202.296
• Mol File: 97597-31-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: rac-2-cyclohexylidene-1-phenylethan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: rac-2-cyclohexylidene-1-phenylethan-1-ol(97597-31-4)
• EPA Substance Registry System: rac-2-cyclohexylidene-1-phenylethan-1-ol(97597-31-4)

Safety Data

• Hazardous Substances Data: 97597-31-4(Hazardous Substances Data)

Upstream product

• 23904-33-8 (iodomethylene)cyclohexane 
• 100-52-7 benzaldehyde 
• 253797-51-2 1-[(2-hydroxy-2-phenyl-1-phenylsulfanyl)ethyl]cyclohexanol 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 5452-52-8 2-cyclohexylidene-1-phenyl-1-ethanone 
• 57213-26-0 1-(2-oxo-2-phenylethyl)cyclohexanol 
• 108-94-1 cyclohexanone 
• 3561-67-9 bis(phenylthio)methane 

Relevant articles and documents

Asymmetric transfer hydrogenation of unsaturated ketones; factors influencing 1,4- vs 1,2- regio- and enantioselectivity, and alkene vs alkyne directing effects

A detailed study has been completed on the asymmetric transfer hydrogenation (ATH) of a series of enones using Ru(II) catalysts. Electron-rich rings adjacent to the C[dbnd]O group reduce the level of C[dbnd]O reduction compared to C[dbnd]C. The ATH reaction can readily discriminate between double and triple bonds adjacent to ketones, reducing the double bond but leaving a triple bond intact in the major product.

Methane-derived polyanionic synthons from bis(phenylthio)methane

Successive treatment of bis(phenylthio)methane (1) with (a) n-butyllithium at 0°C, (b) a carbonyl compound [(t)BuCHO, Me2CO, Et2CO, (CH2)5CO] at -40°C, (c) lithium and a catalytic amount of DTBB (5%) and (d) a s