97651-29-1

Basic information

• Product Name: 3-Pyridinecarboxylic acid, 5-cyano-1,6-dihydro-4-(4-methoxyphenyl)-2-methyl-6-thioxo-, ethyl ester
• CAS NO: 97651-29-1
• Molecular Formula: C17H16N2O3S
• Molecular Weight: 328.392
• Mol File: 97651-29-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Pyridinecarboxylic acid, 5-cyano-1,6-dihydro-4-(4-methoxyphenyl)-2-methyl-6-thioxo-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pyridinecarboxylic acid, 5-cyano-1,6-dihydro-4-(4-methoxyphenyl)-2-methyl-6-thioxo-, ethyl ester(97651-29-1)
• EPA Substance Registry System: 3-Pyridinecarboxylic acid, 5-cyano-1,6-dihydro-4-(4-methoxyphenyl)-2-methyl-6-thioxo-, ethyl ester(97651-29-1)

Safety Data

• Hazardous Substances Data: 97651-29-1(Hazardous Substances Data)

Upstream product

• 39145-31-8 2-cyano-3-(4-methoxyphenyl)thioacrylamide 
• 41867-20-3 ethyl (E)-3-aminobut-2-enoate 
• 141-97-9 ethyl acetoacetate 
• 68029-57-2 2-cyano-3-(4-methoxyphenyl)thioacrylamide 
• 106763-17-1 4-methoxybenzylidenecyanothioacetamide 

Downstream Products

• 123534-10-1 5-Cyano-4-(4-methoxy-phenyl)-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-6-thioxo-1,6-dihydro-pyridine-3-carboxylic acid ethyl ester 
• 868682-34-2 (3-cyano-5-ethoxycarbonyl-4-(4'-methoxyphenyl)-6-methyl)pyridin-2-ylthioacetamide 
• 723745-46-8 3-amino-5-ethoxycarbonyl-4-(4'-methoxyphenyl)-6-methylthieno[2,3-b]pyridine-2-carboxamide 
• 1013663-46-1 C₂₅H₂₃N₃O₄S 
• 723745-20-8 C₂₅H₂₃N₃O₄S 
• 1013663-48-3 C₂₇H₂₅N₃O₅S 
• 723745-24-2 C₂₇H₂₅N₃O₅S 
• 1013663-47-2 C₂₆H₂₅N₃O₄S 
• 1013663-52-9 C₂₆H₂₅N₃O₄S 
• 723745-18-4 C₂₅H₂₂ClN₃O₄S 
• 1013663-53-0 C₂₅H₂₂ClN₃O₄S 
• 1013663-49-4 C₂₈H₂₇N₃O₆S 
• 1013663-54-1 C₂₈H₂₇N₃O₆S 
• 1013663-50-7 C₂₇H₂₅N₃O₆S 

Relevant articles and documents

Fused thieno[2,3-b]pyridines: Synthesis and characterization of new condensed pyridothienopyrimidines

Reaction of cyanopyridine-2(1H)-thiones 2a,b with chloroacetonitrile gave the corresponding 3-aminothieno[2,3-b]pyridine-2-carbonitriles 4a,b. Condensation of 4a,b with triethyl orthoformate produced the methanimidate derivatives 6a,b which upon treatment

REACTIONS WITH CYANOTHIOACETAMIDE DERIVATIVES: SYNTHESIS AND REACTIONS OF SOME PYRAZOLOPYRIDINE DERIVATIVES

The ylidene derivatives of cyanothioacetamide 1a-d reacted with ethyl acetoacetate to give the pyridinethiol derivatives 2a-d.Compounds 2a-d were used as starting material for the synthesis of several heterocyclic compounds.Reaction with hydrazine hydrate, ethyl iodide, methyl chloroacetate and α-chloro ethyl acetoacetate gave the pyridine and annelated pyridine derivatives 5a-d, 6a-d, 7a, 8b-d, and 12a-d, respectively.Compounds 7a, 8b-d and 12a-d reacted with hydrazine hydrate to yield the annelated pyridines 10a-d and 15a-d, respectively.Key words: Cyanothioacetamide; pyridines; thienopyridines; pyrazolopyridines; thienospiropyrazolopyridines.

α,β-Unsaturated nitriles in heterocyclic synthesis. Novel synthesis of pyridines and thieno[2,3-b]pyridine derivatives

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