97691-22-0

Basic information

• Product Name: Pyridine, 2-(1,1-dimethylethyl)-5-phenyl-
• CAS NO: 97691-22-0
• Molecular Formula: C15H17N
• Molecular Weight: 211.307
• Mol File: 97691-22-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-(1,1-dimethylethyl)-5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-(1,1-dimethylethyl)-5-phenyl-(97691-22-0)
• EPA Substance Registry System: Pyridine, 2-(1,1-dimethylethyl)-5-phenyl-(97691-22-0)

Safety Data

• Hazardous Substances Data: 97691-22-0(Hazardous Substances Data)

Upstream product

• 1008-88-4 3-phenylpyridine 
• 38442-51-2 tert-butylmercury chloride 
• 156020-80-3 2,2-dichloro-1-phenylcyclopropanecarbaldehyde diethyl acetal 
• 80234-04-4 2-phenylacrylaldehyde diethyl acetal 
• 5813-64-9 2.2-dimethylpropylamine 
• 122-78-1 phenylacetaldehyde 
• 156021-03-3 [1-(2,2-Dichloro-1-phenyl-cyclopropyl)-meth-(E)-ylidene]-(2,2-dimethyl-propyl)-amine 
• 122801-51-8 2,2-dichloro-1-phenylcyclopropane-1-carbaldehyde 

Relevant articles and documents

Cross Mannich Reaction of Aldehydes; Efficient Synthesis of Substituted Pyridines

Symmetrically and unsymmetrically substituted pyridines were obtained in highly efficient one-pot procedures starting from α-unbranched aldehydes and iminium salts.

Thermal Rearrangement of N-Arylmethyl- and N-Alkyl-2,2-dihalogenocyclopropyl Imines

An extended study of the thermal isomerization of 1-substituted 2,2-dihalogenocyclopropyl imines is reported.The thermolysis of N-arylmethyl-2,2-dichlorocyclopropanecarbaldimines 15a-h produces 2-aryl- 16a-h and 2-aryl-4-chloro-pyridine derivatives 17a-h, while N-cyclopropyl imines 15i, j yielded N-alyklchloropyrroles.The 2,2-dibromocyclopropane analogue undergoes thermolysis at lower temperatures.An ionic mechanism triggered by the halide ion dissociation is proposed for the thermal rearrangement on the basis of a study using deuterated imine 15m, and the effects of additives and solvents.On the other hand, difluorocyclopropyl imine undergoes a homolytic cleavage of cyclopropane 1,3-bond with lower activation energy than the dichlorocyclopropyl imine, and afforded the N-alykl-3-fluoropyrrole derivative preferentially.