97691-25-3

Basic information

• Product Name: Quinoline, 2-(1,1-dimethylethyl)-4-methyl-
• CAS NO: 97691-25-3
• Molecular Formula: C14H17N
• Molecular Weight: 199.296
• Mol File: 97691-25-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Quinoline, 2-(1,1-dimethylethyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 2-(1,1-dimethylethyl)-4-methyl-(97691-25-3)
• EPA Substance Registry System: Quinoline, 2-(1,1-dimethylethyl)-4-methyl-(97691-25-3)

Safety Data

• Hazardous Substances Data: 97691-25-3(Hazardous Substances Data)

Upstream product

• 491-35-0 C₆H₄NCH₂CHCCH₂ 
• 94-36-0 dibenzoyl peroxide 
• 52562-19-3 2-isopropenylaniline 
• 630-19-3 pivalaldehyde 
• 67-56-1 methanol 
• 950818-69-6 2-(2-aminophenyl)-5,5-dimethylhex-3-yn-2-ol 

Relevant articles and documents

SILVER-MEDIATED OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS BY PEROXOCOMPOUNDS. NEW SOURCES OF CARBON-CENTERED RADICALS FOR HETEROAROMATIC SUBSTITUTION

The silver catalyzed oxidative decarboxylation of carboxylic acids by aroylperoxides, percarbonates and perborate provides new sources of alkyl radicals useful for selective substitution of lepidine.

Molecule-Induced Homolysis versus "Concerted Oxenoid Oxygen Insertion" in the Oxidation of Organic Compounds by Dimethyldioxirane

Evidence for a molecule-induced homolysis of dimethyldioxirane by several classes of organic compounds (alkanes, alkenes, ethers, alcohols, aldehydes, iododerivatives) is reported. Carbon-centered radicals, arising from alkanes, ethers, and aldehydes, are trapped by CBrCl3 or protonated quinolines. The dramatic influence of oxygen in these reactions, as well as the formation of products of induced homolysis of the dioxirane by carbon-centered radicals (CH4, CH3OH, CH3COOCH3, ROCOCH3, CH3COOCH2COCH3), strongly supports a radical mechanism. With alkenes and iodo derivatives the induced homolysis would lead to diradical intermediates, whose very fast fragmentation would prevent detection, but circumstantial evidence supports a radical mechanism.

A Convenient Synthesis of Substituted Quinolines by Thermal Electrocyclic Rearrangement of o-Vinyl Anils under Nonacidic Conditions

Anils 8a-g (Table II) underwent smooth rearrangement and oxidation to the quinolines 9a-g at 155-200 deg C via formation of the 2-3 carbon-carbon bond.These cyclizations proceeded in high yields under nonacidic conditions.It was often possible to prepare