97802-08-9

Basic information

• Product Name: 1,10-Phenanthroline, 4,7-bis(4-broMophenyl)-
• Synonyms: 1,10-Phenanthroline, 4,7-bis(4-broMophenyl)-;4,7-Bis(4-broMophenyl)-1,10-phenanthroline;1,10-Phenthroline, 4,7-bis(4-broMophenyl)-
• CAS NO: 97802-08-9
• Molecular Formula: C₂₄H₁₄Br₂N₂
• Molecular Weight: 490.18936
• EINECS: 200-258-5
• Mol File: 97802-08-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 612.704 °C at 760 mmHg
• Flash Point: 324.352 °C
• Appearance: /
• Density: 1.596 g/cm³
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: 4.14±0.10(Predicted)
• CAS DataBase Reference: 1,10-Phenanthroline, 4,7-bis(4-broMophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-Phenanthroline, 4,7-bis(4-broMophenyl)-(97802-08-9)
• EPA Substance Registry System: 1,10-Phenanthroline, 4,7-bis(4-broMophenyl)-(97802-08-9)

Safety Data

• Hazardous Substances Data: 97802-08-9(Hazardous Substances Data)

Usage

General Description

1,10-Phenanthroline, 4,7-bis(4-bromophenyl)- is a chemical compound with the molecular formula C30H20Br2N2. It is a derivative of the heterocyclic compound phenanthroline, which is commonly used as a chelating agent in coordination chemistry. This particular derivative contains two 4-bromophenyl groups attached at the 4 and 7 positions of the phenanthroline ring. 1,10-Phenanthroline, 4,7-bis(4-bromophenyl)- has potential applications in the fields of analytical chemistry, biochemistry, and material science, particularly in the development of luminescent materials, catalysts, and sensors. Its unique structure and properties make it a valuable building block for the synthesis of various organic and inorganic compounds with specific functional properties.

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Downstream Products

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Relevant articles and documents

Structure and Phase Transition of 4,7-Bis-(4′-cyano-biphenyl-4-yl)-[1, 10]phenanthroline

4,7-Bis-(4′-cyano-biphenyl-4-yl)-[1, 10]phenanthroline (cnbiphphen) is synthesized from a palladium mediated coupling between 4-cyanobenzene boronic acid and 4,7-bis(4-bromophenyl)-[1,10]phenanthroline. The single crystal X-ray structure was measured at b

Properties and structure of two fluorinated 1,10-phenanthrolines

We report the synthesis, X-ray structure, absorbance and emission of 4,7-bis(4-fluorophenyl)-1,10-phenanthroline and 4,7-bis-(4′-trifluoromethyl-biphenyl-4-yl)-1,10-phenanthroline. 4,7-Bis(4-fluorophenyl)-1,10-phenanthroline was synthesized by successive Skraup reactions and features absorbance at 274 nm and emission at 384 nm while 4,7-bis-(4′-trifluoromethyl-biphenyl-4-yl)-1,10-phenanthroline featured absorbance at 283 nm and emission at 400 nm. The structures show molecular stacking of the phenyl groups and phenanthroline structure and longitudinal fluorine atom associations within the crystal lattice. Furthermore, the three fused rings of the 4,7-bis(4-fluorophenyl)-1,10-phenanthroline unit exhibited torsion up to 13.97(9)° throughout the crystal lattice whereas no torsion is observed for 4,7-bis-(4′-trifluoromethyl-biphenyl-4-yl)-1,10-phenanthroline.

Luminescent Metal Complexes. Part 5. Luminescence Properties of Ring-substituted 1,10-Phenanthroline Tris-complexes of Ruthenium(II)

The absorption characteristics, emission spectra, luminescent quantum yields, and lifetimes are reported for 24 ruthenium(II) tris-1,10-phenanthroline complexes in EtOH-MeOH solution.Quantum yields fall between 0.019 and 0.403, the highest values being re