98009-22-4

Basic information

• Product Name: Ethyl (5S,6R)-5-tert-Butyldiphenylsilyloxy-6,7-O-isopropylideneheptanoate
• Synonyms: Ethyl (5S,6R)-5-tert-Butyldiphenylsilyloxy-6,7-O-isopropylideneheptanoate
• CAS NO: 98009-22-4
• Molecular Weight: 484.708
• Mol File: 98009-22-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethyl (5S,6R)-5-tert-Butyldiphenylsilyloxy-6,7-O-isopropylideneheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl (5S,6R)-5-tert-Butyldiphenylsilyloxy-6,7-O-isopropylideneheptanoate(98009-22-4)
• EPA Substance Registry System: Ethyl (5S,6R)-5-tert-Butyldiphenylsilyloxy-6,7-O-isopropylideneheptanoate(98009-22-4)

Safety Data

• Hazardous Substances Data: 98009-22-4(Hazardous Substances Data)

Upstream product

• 133988-95-1 (S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-pent-2-ynoic acid ethyl ester 
• 74134-78-4 (2R,3S)-3,4-epoxy-1,2-O-isopropylidenebutane-1,2-diol 
• 72036-30-7 ethyl 3-lithiopropiolate 
• 149859-05-2 1-[2',2'-dimethyl-(4'R)-1',3'-dioxolan-4'-yl]-(1S)-3-butyn-1-ol 
• 383135-46-4 2,2'-dimethyl-1-(4'(R)-1',3'-dioxacyclopentyl)-but-3-yn-1(S/R)-ol 
• 178060-94-1 tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-ynyloxy]-diphenyl-silane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 178060-93-0 Acetic acid (S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-ynyl ester 
• 178060-95-2 (S)-5-(tert-Butyl-diphenyl-silanyloxy)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pent-2-ynoic acid ethyl ester 
• 93292-42-3 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 79308-43-3 (S)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-pentanoic acid ethyl ester 
• 93292-41-2 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal 

Downstream Products

• 98049-75-3 (6E,8E,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((4S,5S)-2-oxo-5-pentyl-[1,3]dioxolan-4-yl)-trideca-6,8,10,12-tetraenoic acid ethyl ester 
• 98049-76-4 (6E,8Z,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((4S,5S)-2-oxo-5-pentyl-[1,3]dioxolan-4-yl)-trideca-6,8,10,12-tetraenoic acid ethyl ester 
• 114144-25-1 (6E,8E,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((2R,3R)-3-pentyl-oxiranyl)-trideca-6,8,10,12-tetraenoic acid ethyl ester 
• 114144-25-1 (6E,8Z,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((2S,3S)-3-pentyl-oxiranyl)-trideca-6,8,10,12-tetraenoic acid ethyl ester 
• 114144-28-4 5S-hydroxy-14,15-LTA₄ 
• 98009-34-8 (6E,8E,10E,12E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-13-((4R,5S)-2-oxo-5-pentyl-[1,3]dioxolan-4-yl)-trideca-6,8,10,12-tetraenoic acid ethyl ester 
• 98049-66-2 (5S,14R,15S)-(6E,8Z,10E,12E)-5-O-tert-butyldiphenylsilyl-14,15-O-carbonyl lipoxin B₄ ethyl ether 
• 98009-27-9 <(4S)-(2E)-4-tert-butyldiphenylsilyloxy-7-carboxyethyl-2-hepten-1-yl>triphenyl phosphonium bromide 
• 98009-26-8 (E)-(S)-8-Bromo-5-(tert-butyl-diphenyl-silanyloxy)-oct-6-enoic acid ethyl ester 
• 98009-25-7 ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-8-hydroxy-6-octenoate 
• 98009-24-6 ethyl (5S)-(6E)-5-tert-butyldiphenylsilyloxy-7-formyl-6-heptenoate 
• 98040-76-7 (S)-5-(tert-Butyl-diphenyl-silanyloxy)-6-oxo-hexanoic acid ethyl ester 
• 98009-23-5 (5S,6R)-5-(tert-Butyl-diphenyl-silanyloxy)-6,7-dihydroxy-heptanoic acid ethyl ester 

Relevant articles and documents

Synthesis of (2E,4E)-dienals by double formyl-olefination with an arsonium salt and its application in the syntheses of lipoxygenase metabolites of arachidonic acid

A new facile route to (2E,4E)-dienals by a double formyl-olefination with arsonium salts has been developed. By this method and with other arsonium reagents in the key step some lipoxygenase metabolites of arachidonic acid, lipoxin A4 and B4 and leukotriene B4, have been synthesized.

SYNTHESIS OF 5S-HYDROXY-14,15 LTA4 A BIOGENIC PRECURSOR TO THE LIPOXINS

A synthesis of 5S-hydroxy-14,15-LTA4 10 an intermediate in the biosynthesis of the lipoxins is described.