983-79-9Relevant articles and documents
Synthesis of 3-(2-Oxo-2,3-dihydrobenzo[b]furan-3-ylidenehydrazono)-2,3- dihydrobenzo[b]furan-2-one
Pulina,Zalesov,Kataev
, p. 861 - 863 (2007)
Reactions of benzophenone and fluoren-9-one hydrazones with (2-hydroxyphenyl)oxoacetic acid gave [carboxy(2-hydroxyphenyl) methylidenehydrazono](2-hydroxyphenyl)acetic acid which underwent intramolecular cyclization with formation of 3-(2-oxo-2,3-dihydrob
Cobalt(II) complex of a diazoalkane radical anion
Bonyhady, Simon J.,Goldberg, Jonathan M.,Wedgwood, Nicole,Dugan, Thomas R.,Eklund, Andrew G.,Brennessel, William W.,Holland, Patrick L.
, p. 5148 - 5150 (2015)
β-Diketiminate cobalt(I) precursors react with diphenyldiazomethane to give a compound that is shown by computational studies to be a diazoalkane radical anion antiferromagnetically coupled to a high-spin cobalt(II) ion. Thermolysis of this complex result
Preparation and application of 5-bromoquinazoline derivative
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Paragraph 0035-0037, (2021/02/16)
The invention discloses a 5-bromoquinazoline derivative shown in the corresponding formula. A synthesis method of the 5-bromoquinazoline derivative compound (I) comprises the following steps: weighing1.18 g of 5-bromoisatin, 2.5503g of ammonium formate an
Grignard reagent dictated copper(I) phosphines catalyzed reductive coupling of diazo compounds: The chemistry beyond carbene generation
Kuzhalmozhi Madarasi, Packirisamy,Sivasankar, Chinnappan
, (2021/12/01)
Copper-dppf catalyzed reductive coupling of diazo compounds through terminal nitrogen is reported. However, copper catalysts are known to produce carbene from diazo compounds; the reaction conditions played an important role in the formation of diazine over carbene generation. Several control experiments have been conducted to understand the reaction mechanism and found that the formation of a copper–Mg heterobimetallic complex would be responsible for the observed reactivity pattern. The reaction produced diazine as a reductive coupling product along with biphenyl as a by-product. All the synthesized diazines have been characterized fully by using analytical and spectroscopic techniques.
Application of chiral oxazoline-copper complex
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Page/Page column 8, (2020/01/25)
An application of a bis{2-[4(R)-phenyl-4,5-dihydro]-2-oxazoline}phenol-copper complex with a chemical formula shown in the description is characterized in that the complex has a good catalysis performance when used as a catalyst for a reaction of diphenyl