98391-71-0

Basic information

• Product Name: [palladium(tricyclohexylphosphine)(η1,η3-octadienediyl)]
• Synonyms: [palladium(tricyclohexylphosphine)(η1,η3-octadienediyl)]
• CAS NO: 98391-71-0
• Molecular Weight: 495.037
• Mol File: 98391-71-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [palladium(tricyclohexylphosphine)(η1,η3-octadienediyl)](CAS DataBase Reference)
• NIST Chemistry Reference: [palladium(tricyclohexylphosphine)(η1,η3-octadienediyl)](98391-71-0)
• EPA Substance Registry System: [palladium(tricyclohexylphosphine)(η1,η3-octadienediyl)](98391-71-0)

Safety Data

• Hazardous Substances Data: 98391-71-0(Hazardous Substances Data)

Upstream product

• 106-99-0 buta-1,3-diene 
• 2622-14-2 tricyclohexylphosphine 
• 1271-03-0 allyl(cyclopentadiene)palladium(II) 

Downstream Products

• 98268-17-8 Pd(P(C₆H₁₁)3)(CH₂CHCOOCH₃)2 
• 98268-18-9 (Pd(SC₆H₁₁)2(P(C₆H₁₁)3))2 
• 98268-11-2 PdCl(P(C₆H₁₁)3)(C₈H₁₃) 
• 98268-14-5 Pd(OCOCH₃)(P(C₆H₁₁)3)(C₈H₁₃) 

Relevant articles and documents

Intermediates in the palladium-catalyzed reactions of 1,3-dienes. 2. Preparation and structure of (η1,η3-octadienediyl)palladium complexes

A series of (η1,η3-octadienediyl)palladium complexes, [Pd(L)(η1,η3-C8H12)] and [Pd(L)(η1,η3-Me2C8H 10)], has been prepared by reacting bis(η3-2-methylallyl)palladium with donor ligands and butadiene or isoprene. The reactions occur in a stepwise manner through the intermediacy of [Pd(L)(η1,η3-allyl)2] and [{Pd-(L)(μ-η3-allyl)}2] complexes. The η1,η3-octadienediyl systems react with olefins such as methyl acrylate to give (η2-olefin)2Pd-L complexes and with acids to give (η2,η3-octadienyl)- and/or (η3-octadienyl)palladium complexes.