98405-65-3

Basic information

• Product Name: Ethanone, 1-(2,4,6-cycloheptatrien-1-yl)-2-phenyl-
• CAS NO: 98405-65-3
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• Mol File: 98405-65-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(2,4,6-cycloheptatrien-1-yl)-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2,4,6-cycloheptatrien-1-yl)-2-phenyl-(98405-65-3)
• EPA Substance Registry System: Ethanone, 1-(2,4,6-cycloheptatrien-1-yl)-2-phenyl-(98405-65-3)

Safety Data

• Hazardous Substances Data: 98405-65-3(Hazardous Substances Data)

Upstream product

• 4250-02-6 1-diazo-3-phenyl-2-propanone 
• 71-43-2 benzene 

Relevant articles and documents

SYNTHESIS OF CYCLOHEPTA-1,3,5-TRIENES BY THE REACTION OF AROMATIC HYDROCARBONS WITH DIAZO COMPOUNDS IN THE PRESENCE OF TRANSITION METAL COMPLEXES

A preparative method has been developed for the synthesis of cyclohepta-1,3,5-trienes, using a reaction of aromatic hydrocarbons with diazomethane, methyldiazoacetate, adamantanoyldiazomethane, and 1-diazo-3-phenylpropan-2-one, with rhodium trifluoroacetate as catalyst.The order of activity and the relative reactivity coefficients of substituted benzenes have been determined, and the link between these characteristics and the energy of the highest occupied molecular orbital of the aromatic ring has been established.In catalyzed reactions of benzenes with diazomethaneor methyldiazoacetate, leading to cycloheptatrienes, effects of chemical polarization of the ring have not been observed.