98555-19-2

Basic information

• Product Name: N-acetoxy-2,4-dinitrobenzenamine
• Synonyms: N-acetoxy-2,4-dinitrobenzenamine
• CAS NO: 98555-19-2
• Molecular Weight: 241.16
• Mol File: 98555-19-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-acetoxy-2,4-dinitrobenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-acetoxy-2,4-dinitrobenzenamine(98555-19-2)
• EPA Substance Registry System: N-acetoxy-2,4-dinitrobenzenamine(98555-19-2)

Safety Data

• Hazardous Substances Data: 98555-19-2(Hazardous Substances Data)

Upstream product

• 2486-07-9 2,4-dinitrophenyl phenyl ether 
• 119-27-7 2,4-dinitroanisole 
• 51348-06-2 N-(2,4-dinitrophenyl)hydroxylamine 
• 75-36-5 acetyl chloride 
• 830-03-5 4-nitrophenol acetate 
• 108-24-7 acetic anhydride 

Downstream Products

• 28943-91-1 2,2',4,4'-tetranitroazoxybenzene 
• 18771-86-3 5-nitrobenzofuroxan 
• 97-02-9 2,4-Dinitroanilin 

Relevant articles and documents

Reaction of N-Acyloxy-2-nitrobenzenamines.I. Thermolysis in Benzene or Bromobenzene

N-Acyloxy-2-nitro- and N-acyloxy-2,4-dinitro-benzenamines have been pyrolysed at 140 deg C in benzene or bromobenzene solution.Homolysis ( to form RCO2-radical and ArNH-radical) is ruled out since virtually all the carboxylate is isolated as carboxylic acid.This acid might arise via a concerted elimination process ( the other product being a benzofurazan 1-oxide), or via heterolysis to ArNH01+, RCO21- with subsequent transfer of proton, and cyclization of the singlet 2-nitrophenylnitrene.These simple reactions compete with bimolecular reactions of products with substrate, in which the corresponding amine, azoxy compound and acid anhydride are generated.Attempts to synthesize N-tosyloxy derivatives of nitrobenzenamines gave only thermal decomposition products.N-Trifluoroacetoxy-2,4-dinitrobenzenamine was isolated as a crude product which detonated violently.