98582-94-6Relevant articles and documents
THE BEHAVIOR OF ALKOXIDES WITH ALLYL(CHLOROMETHYL)DIMETHYLSILANES AND (CHLOROMETHYL)DIMETHYLVINYLSILANE; THE ABILITIES OF ALLYL AND VINYL GROUPS TO MIGRATE FROM PENTACOORDINATE SILICON
Sans, E. A.,Shechter, H.
, p. 1119 - 1122 (1985)
Sodium methoxide in tetrahydrofuran attacks silicon in allyl(chloromethyl)-dimethylsilane and in (chloromethyl)dimethylvinylsilane with displacement of chloride and 1,2-migration of the allyl and the vinyl groups to give 1-(3-butenyl)methoxydimethylsilane and allylmethoxydimethylsilane.