98639-91-9

Basic information

• Product Name: 1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)
• Synonyms: 1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)
• CAS NO: 98639-91-9
• Molecular Formula: C₈H₈N₂OS
• Molecular Weight: 0
• Product Categories: BENZIMIDAZOLE
• Mol File: 98639-91-9.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)(98639-91-9)
• EPA Substance Registry System: 1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)(98639-91-9)

Safety Data

• Hazardous Substances Data: 98639-91-9(Hazardous Substances Data)

Upstream product

• 7152-24-1 2-methylsulfanylbenzimidazole 
• 134469-07-1 Benzimidazol-2-thiol 

Downstream Products

• 112951-87-8 2-(1H-Benzimidazol-2-yl thio)-N,N-dimethyl benzenamine 
• 51290-77-8 2-(benzylthio)-1H-benzo[d]imidazole 
• 699-10-5 1-benzyl-2-methyldisulfide 
• 69104-73-0 2-<(2-aminophenyl)thio>-1H-benzimidazole 
• 135430-18-1 [2-(1H-Benzoimidazol-2-ylsulfanyl)-phenyl]-methyl-amine 
• 2360-29-4 2-(phenylsulfanyl)-1H-benzimidazole 
• 110143-85-6 2-Benzenesulfinyl-1H-benzoimidazole 
• 104340-32-1 (benzimidazol-2-yl) benzyl sulfoxide 
• 104547-40-2 2-<(2-aminophenyl)sulfinyl>-1H-benzimidazole 
• 135430-49-8 [2-(1H-Benzoimidazole-2-sulfinyl)-phenyl]-methyl-amine 
• 112951-55-0 2-(1H-Benzimidazol-2-yl sulphinyl)-N,N-dimethyl benzenamine 
• 135430-26-1 2-<(2-(glycylamino)phenyl)thio>-1H-benzimidazole 
• 135430-50-1 2-Amino-N-[2-(1H-benzoimidazole-2-sulfinyl)-phenyl]-acetamide 
• 135430-31-8 (S)-2-Amino-4-methyl-pentanoic acid [2-(1H-benzoimidazol-2-ylsulfanyl)-phenyl]-amide 

Relevant articles and documents

An environmentally benign and selective electrochemical oxidation of sulfides and thiols in a continuous-flow microreactor

A practical and environmentally benign electrochemical oxidation of thioethers and thiols in a commercially-available continuous-flow microreactor is presented. Water is used as the source of oxygen to enable the oxidation process. The oxidation reaction utilizes the same reagents in all scenarios and the selectivity is solely governed by the applied potential. The procedure exhibits a broad scope and good functional group compatibility providing access to various sulfoxides (15 examples), sulfones (15 examples) and disulfides (6 examples). The use of continuous flow allows the optimal reaction parameters (e.g. residence time, applied voltage) to be rapidly assessed, to avoid mass- and heat-transfer limitations and to scale the electrochemistry.

Polyoxomolybdate-Calix[4]arene Hybrid: A Catalyst for Sulfoxidation Reactions with Hydrogen Peroxide

An easily accessible polyoxomolybdate-calix[4]arene hybrid 1 has been synthesized and applied as a heterogeneous catalyst in the sulfoxidation of thioethers to sulfoxides and to sulfones under strictly stoichiometric amounts of 30% H2O2 in CH3CN as the solvent. This study represents the first promising example of successful employment of calixarenes-polyoxometalate (POM) hybrid materials in the area of catalytic oxidations.

Oxidation of polyfunctional sulfides with chlorine dioxide

3-Benzylsulfanyl-4,5-diphenyl-4H-1,2,4-triazole, 5-methylsulfanyl-1-phenyl- 1H-tetrazole, 2-methylsulfanyl-1H-benzimidazole, 2-benzylsulfanyl-1H- benzimidazole, and 1-butylsulfanyl-4-nitrobenzene were oxidized to the corresponding sulfoxides with chlorine