98689-60-2Relevant articles and documents
Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes
Itoh, Taisuke,Shimizu, Yohei,Kanai, Motomu
supporting information, p. 7528 - 7531 (2016/07/06)
We report the first copper-catalyzed regio- and stereoselective borylalkylation of dialkylsubstituted internal alkynes with bis(pinacolato)diboron and alkyl halides. A catalytically generated borylcopper species containing a novel π-accepting N-heterocycl
Preparation of iniidazolin-2-iminato molybdenum and tungsten benzylidyne complexes: A new pathway to highly active alkyne metathesis catalysts
Haberlag, Birte,Wu, Xian,Brandhorst, Kai,Grunenberg, Joerg,Daniliuc, Constantin G.,Jones, Peter G.,Tamm, Matthias
supporting information; experimental part, p. 8868 - 8877 (2010/09/08)
The reaction of [PhC=MBr3(dme)] (dme = 1,2-dimethoxyethane) with the hexafluoro-fert-butoxides LiJ. or KX [X = OC(CF3)2Me] afforded the benzylidyne complexes [PhC=MX3(dme)] (2a: M = W, 2b: M = Mo), which further
Highly selective hydrogenation of multiple carbon-carbon bonds promoted by nickel(0) nanoparticles
Alonso, Francisco,Osante, I?aki,Yus, Miguel
, p. 93 - 102 (2007/10/03)
A new method for the highly stereoselective cis semihydrogenation of internal alkynes, semihydrogenation of terminal alkynes, reduction of dienes to alkenes, and reduction of alkynes and alkenes to alkanes is described based on in situ generated both Ni(0) nanoparticles and molecular hydrogen.