98750-73-3Relevant articles and documents
Simple and stereoselective synthetic route to (E)-1-alkenyl sulfoxides via terminal alkynes
Zhong,Guo,Huang
, p. 588 - 589 (2007/10/03)
Terminal alkynes 1 react with Cp2Zr(H)Cl (Cp = η5-C5H5) to give organozirconium (IV) complexes 2, which are trapped with sulfuryl chloride to afford (E)-1-alkenyl sulfoxides 3.
Additive Pummerer Rearrangements. Asymmetric Synthesis of (-)-Methyl Jasmonate
Posner, Gary H.,Asirvatham, Edward,Ali, Syed F.
, p. 542 - 543 (2007/10/02)
Examples of mild, additive Pummerer rearrangements are given; one example involves asymmetric carbon-carbon bond formation as the key step for synthesis of (-)-methyl jasmonate.