98775-15-6

Basic information

• Product Name: 2-(cyclohex-1-enyl)ethyl radical
• CAS NO: 98775-15-6
• Molecular Weight: 109.191
• Mol File: 98775-15-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(cyclohex-1-enyl)ethyl radical(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(cyclohex-1-enyl)ethyl radical(98775-15-6)
• EPA Substance Registry System: 2-(cyclohex-1-enyl)ethyl radical(98775-15-6)

Safety Data

• Hazardous Substances Data: 98775-15-6(Hazardous Substances Data)

Upstream product

• 185-65-9 spiro[2.5]octane 

Relevant articles and documents

Dynamics of Internal Rotation in 2-(Cycloalkenyl)ethyl Radicals

2-(Cycloalkenyl)ethyl radicals having C4 to C7 rings were observed by e.s.r. spectroscopy.The barriers to rotation about the -Cβ bonds were determined from the temperature variation of the β-hydrogen hyperfine splitting and shown to decrease with increasing ring size.In all cases, the preferred conformation about the Cβ-Cγ bond was found to be the one in which the -Cβ bond makes an angle of 90 deg with the plane of the ring.Exchange broadening due to restricted rotation about the Cβ-Cγ bond was observed and the rotation barriers were determined for the radicals with C6 and C7 rings.The radicals were studied using the semi-empirical MINDO/3 and MNDO methods and the corresponding hydrocarbons were investigated by the MM2 force field approach.The variation in the rotational barrier heights were attributed to steric effects.