98793-56-7Relevant articles and documents
1,2-Thio group migration in Rh(II) carbene reactions
Xu, Feng,Shi, Weifeng,Wang, Jianbo
, p. 4191 - 4194 (2007/10/03)
A series of β-thio group substituted α-diazo carbonyl compounds have been prepared by nucleophilic substitution reactions of thiophenol, thionaphthol, or benzyl mercaptan with β-acetoxy-α-diazo carbonyl compounds. The diazo decomposition of these diazo ca
Phenylthio Migrations in Rearrangements of 2,2-Bisphenylthioethanols
Blatcher, Philip,Warren, Stuart
, p. 1055 - 1066 (2007/10/02)
Thionyl chloride causes rearrangement of the title compounds to give 2,3-bisphenylthiopropenes (12) by a phenylthio shift.The products undergo phenylthio shifts on exposure to light.Some applications to synthesis are described.