99142-09-3Relevant articles and documents
Stereochemistry of an Oxidative 1,4-Fragmentation of γ-Stannyl Alcohols with a Hypervalent Organoiodine Compound and the Synthesis of erythro-6-Acetoxyhexadecan-5-olide
Ochiai, Masahito,Ukita, Tatsuzo,Nagao, Yoshimitsu,Fujita, Eiichi
, p. 637 - 638 (2007/10/02)
Iodine(III)-mediated oxidative 1,4-fragmentation of the 2,3-trans- and 2,3-cis-3-stannyl alcohols, (6a,b) and (6c), proceeds stereospecifically to give the E- and Z-enals, (7) and (8), respectively, and stereoselective synthesis of the mosquito pheromone,