99188-19-9Relevant articles and documents
NOUVEAUX DECONTAMINANTES. DESTRUCTION OXYDATIVE D'UN SILIMI DE L'YPERITE: LE PHENYL-2 CHLORO-2' DIETHYLSULFURE PAR LE MONOPERSULFATE DE POTASSIUM
Leblanc, Andre,Fosset, Laurent,Magnaud, Gilbert,Delmas, Gerard,Desgranges, Michel,et al.
, p. 141 - 146 (2007/10/02)
The reaction of potassium monopersulfate (CUROX or OXONE) with 2-phenyl 2'-chloro diethylsulfide PhCH2CH2SCH2CH2Cl goes to completion in a very short time.The intermediate chlorinated sulfone PhCH2CH2SO2CH2CH2Cl leads to the phenethylvinylsulfone PhCH2CH2SO2CH=CH2 by HCl elimination. Key words: decontamination; potassium monopersulfate; yperite.
NOUVEAUX DECONTAMINANTS. DESTRUCTION DU PARAOXON ET D'UN SIMILI DE L'YPERITE PAR QUELQUES ACIDES HYDROXAMIQUES
Lion, C.,Hedayatullah, M.,Bauer, P.,Boukou-Poba, J. P.,Charvy, C.,et al.
, p. 617 - 621 (2007/10/02)
A new series of hydroxamic acids 1-4 has been used in the destruction of paraoxon (O,O-diethyl O-paranitrophenylphosphate) and a mustard-related compound (2-chloro 2'-phenyl diethylsulfide).These hydroxamic acids are N-alkyl substituted isonicotinhydroxamic acid 1, and quinolone derivatives 2 norbornyl- and adamantylhydroxamic acids 3 and 4.The latter are very reactive and the addition of certain surfactants enhances the rate of the reaction.Very short half-lives are obtained with these compounds.
