99307-07-0Relevant articles and documents
Bond-Weakening Catalysis: Conjugate Aminations Enabled by the Soft Homolysis of Strong N-H Bonds
Tarantino, Kyle T.,Miller, David C.,Callon, Ted A.,Knowles, Robert R.
supporting information, p. 6440 - 6443 (2015/06/08)
The ability of redox-active metal centers to weaken the bonds in associated ligands is well precedented, but has rarely been utilized as a mechanism of substrate activation in catalysis. Here we describe a catalytic bond-weakening protocol for conjugate a
Photochemical Isomerization of O-Allyl and O-But-3-enyl Thiocarbamates
Sakamoto, Masami,Yoshiaki, Mitsuru,Takahashi, Masaki,Fujita, Tsutomu,Watanabe, Shoji
, p. 373 - 378 (2007/10/02)
The photochemistry of O-allyl and O-but-3-enyl thiocarbamates has been studied.Photolysis of benzene solutions of O-allyl N-phenylthiocarbamates gave S-allyl N-phenylthiocarbamates.The 1,3-allyl migration from the oxygen to the sulfur involves a concerted process.The same type of 1,3-migration took place in the conversion of O-benzyl N-phenylthiocarbamate into S-benzyl N-phenylthiocarbamate.Irradiation of O-but-3-enylthiocarbamates produced iminooxolanes via aminothietane intermediates.In the case of O-but-3-enyl N-benzoyl-N-phenylthiocarbamates, 3-(benzoylmethyl)-2-phenyliminooxolanes were obtained via a ring opening of the aminothietanes involving a 1,5-benzoyl shift.
N-Nitroso Compounds. IV. Reaction of N-Nitrosourea with Thiol. A New Synthesis of Thiocarbamic S-Esters
Yoshida, Kitaro,Isobe, Masayoshi,Yano, Kazuyuki,Nagamatsu, Kazuo
, p. 2143 - 2144 (2007/10/02)
Thirteen thiocarbamic S-esters have been prepared in good yield by the reaction of thiol with substituted N-methyl-N-nitrosourea in anhydrous acetonitrile.