99315-43-2Relevant articles and documents
LEWIS ACID MEDIATED 1,2-ASYMETRIC lk-INDUCTION TO α-ALKOXYALDEHIDE: SYNTHESIS OF α-NONSUBSTITUTED β,γ-syn-DIHYDROXYKETONE AND ESTER
Uenishi, Jun-ichi,Tomozane, Hideo,Yamato, Masatoshi
, p. 3467 - 3470 (1985)
Lewis acid mediated reactions of methylthio substituted silyl enolate or ketene silyl acetal to α-alkoxyaldehyde give syn diols.A novel stereocontrolled synthesis of α-nonsubstituted β,γ-dihydroxyketone and ester is described.