99321-88-7Relevant articles and documents
Palladium nano-particles as a recyclable catalyst for C-O bond formation under solvent free conditions
Khan, Ajmal,Zhang, Junjie,Khan, Shahid
, p. 4116 - 4120 (2020)
The development of green, economical and sustainable chemical processes is one of the primary challenges in organic chemistry. Herein, we report a recoverable heterogeneous palladium catalyst for the stereoselective synthesis of multi-functionalized allylic ethers under solvent free conditions. This method is based on in situ generated PdNP catalyzed O-allylation of alcohols with vinyl cyclic carbonates. Solvent-free conditions, easily recoverable catalysts, efficient recycling, and operational simplicity make the protocol green, economic and sustainable.
Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers
Xie, Jianing,Guo, Wusheng,Cai, Aijie,Escudero-Adán, Eduardo C.,Kleij, Arjan W.
supporting information, p. 6388 - 6391 (2017/12/08)
A general methodology for the synthesis of enantioenriched tertiary allylic aryl ethers through Pd-catalyzed decarboxylative reactions of vinyl cyclic carbonates and phenols is presented. Switching of the regioselectivity toward the formation of linear products by a judicious choice of the ligand is also reported.