99337-73-2

Basic information

• Product Name: 1,2,3,6-tetra-O-acetyl-4-O-trityl-β-D-glucopyranose
• Synonyms: 1,2,3,6-tetra-O-acetyl-4-O-trityl-β-D-glucopyranose
• CAS NO: 99337-73-2
• Molecular Weight: 590.627
• Mol File: 99337-73-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,3,6-tetra-O-acetyl-4-O-trityl-β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,6-tetra-O-acetyl-4-O-trityl-β-D-glucopyranose(99337-73-2)
• EPA Substance Registry System: 1,2,3,6-tetra-O-acetyl-4-O-trityl-β-D-glucopyranose(99337-73-2)

Safety Data

• Hazardous Substances Data: 99337-73-2(Hazardous Substances Data)

Upstream product

• 54325-28-9 (2R,3R,4S,5S,6R)-6-Trityloxymethyl-tetrahydro-pyran-2,3,4,5-tetraol 
• 54325-28-9 6-O-trityl-α-D-glucose 
• 2280-44-6 D-Glucose 
• 37074-90-1 1,2,3,4-tetra-O-acetyl-6-O-trityl-β-D-glucopyranose 
• 16721-97-4 trityl perchlorate 
• 27086-15-3 1,2,3,6-tetra-O-acetyl-β-D-glucopyranose 

Downstream Products

• 1726-94-9 trityl isothiocyanate 
• 20764-63-0 β-cellobioseoctaacetate 
• 22352-19-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyl acetate 
• 127066-74-4 1,2,3,6-tetra-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glucopyranosyl)-β-D-glucopyranose 
• 130052-64-1 1,2,3,6-tetra-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-galactopyranosyl)-β-D-glucopyranose 
• 130052-67-4 Acetic acid (2R,3S,4S,5R,6S)-3-acetoxy-2-acetoxymethyl-5-benzyloxy-6-isothiocyanato-tetrahydro-pyran-4-yl ester 
• 604-69-3 β-D-glucose pentaacetate 
• 130052-67-4 3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glucopyranosyl isothiocyanate 
• 127088-73-7 1,2,3,6-tetra-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-O-methyl-α-D-glucopyranosyl)-β-D-glucopyranose 

Relevant articles and documents

Syntheses and 1H- and 13C-Nuclear Magnetic Resonance Spectra of All Positional Isomers of Tetra-O-acetyl-D-glucopyranoses, and Their Monobenzyl and Monotrityl Derivatives

All the isomers of the tetra-O-acetyl-D-glucopyranoses, and their monobenzyl and monotrityl derivatives were synthesized and systematic 1H- and 13C-nuclear magnetic resonance (1H- and 13C-NMR) studies were carried out.Complete assignments of the 1H- and 13C-NMR signals were achieved by 1H- and 13C-decoupling techniques and by the use of a shift reagent and changes of solvents.Moreover, when necessary, 1H- and 13C-shift-correlated 2D NMR spectroscopy at higher frequency (Bruker AM 400) was applied.The shifts on deacetylation, benzylation, and tritylation were estimated on the basis of the 1H- and 13C-chemical shifts of these compounds, and the effects of deacetylation and benzyl- or trityl-substitution are discussed.Keywords - tetra-O-acetyl-D-glucopyranose; monobenzyl tetra-O-acetyl-D-glucopyranose; monotrityl tetra-O-acetyl-D-glucopyranose; 1H-NMR; 13C-NMR; deacetylation shift; benzylation shift; tritylation shift