99436-45-0Relevant articles and documents
Enantioselective chlorinative aldol reaction of α-substituted acroleins catalyzed by chiral phosphine oxides
Kotani, Shunsuke,Hanamure, Takuya,Nozaki, Hirono,Sugiura, Masaharu,Nakajima, Makoto
, p. 282 - 287 (2017)
The enantioselective chlorinative aldol reaction of α-substituted acroleins with aldehydes catalyzed by chiral phosphine oxides is described. A hypervalent silicon complex-derived chloride adds to the α-substituted acroleins to form the corresponding sily
Diastereo- and enantioselective reductive aldol reaction with trichlorosilane using Chiral Lewis bases as organocatalysts
Sugiura, Masaharu,Sato, Norimasa,Sonoda, Yuko,Kotani, Shunsuke,Nakajima, Makoto
supporting information; experimental part, p. 478 - 481 (2010/09/04)
Chiral Lewis base organocatalysts activate trichlorosilane to promote the tandem conjugate reduction/aldol reaction of α, β-unsaturated ketones with aldehydes to give optically active β-hydroxy ketones with good to high syn diastereo- and enantioselectivi
The solution structures of chiral Ti(4+) alkoxides. II. The roles of diolate basicity and side-chain binding group polarity
Bianchet, Stephen,Potvin, Pierre G.
, p. 2256 - 2265 (2007/10/02)
With a view to reproduce the structures in solution of the Katsuki-Sharpless catalyst (the dimeric complex formed by homochiral diisopropyl tartrate with Ti(OiPr)4), five C2-symmetric chiral 2,3-butanediols, related to L-threitol but
