99634-01-2

Basic information

• Product Name: 3-hydroxy-2-(2-methoxyphenoxy)-1-phenyl-1-propanone
• Synonyms: 3-hydroxy-2-(2-methoxyphenoxy)-1-phenyl-1-propanone
• CAS NO: 99634-01-2
• Molecular Weight: 272.301
• Mol File: 99634-01-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-hydroxy-2-(2-methoxyphenoxy)-1-phenyl-1-propanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-hydroxy-2-(2-methoxyphenoxy)-1-phenyl-1-propanone(99634-01-2)
• EPA Substance Registry System: 3-hydroxy-2-(2-methoxyphenoxy)-1-phenyl-1-propanone(99634-01-2)

Safety Data

• Hazardous Substances Data: 99634-01-2(Hazardous Substances Data)

Upstream product

• 19513-80-5 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one 
• 92409-23-9 3-hydroxy-2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propan-1-one 
• 90-05-1 2-methoxy-phenol 
• 70-11-1 α-bromoacetophenone 
• 22675-96-3 2-methoxyphenoxy-3',4'-dimethoxyacetophenone 
• 92409-15-9 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)-1-hydroxy-3-propanol 
• 17078-88-5 1-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)ethanol 
• 227300-29-0 2-(2-methoxyphenoxy)-1-phenylpropane-1,3-diol 
• 10535-17-8 1-(3,4-dimethoxyphenyl)-2-(methoxyphenoxy)propane-1,3-diol 
• 50-00-0 formaldehyd 
• 14385-48-9 2-(2-methoxyphenoxy)-acetophenone 

Downstream Products

• 1252675-90-3 1-(4-benzoyloxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)ethanone 
• 90-05-1 2-methoxy-phenol 
• 98-86-2 acetophenone 
• 98-85-1 1-Phenylethanol 
• 14385-48-9 2-(2-methoxyphenoxy)-acetophenone 
• 7382-68-5 1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)ethanol 
• 22317-35-7 1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)ethan-1-one 
• 38768-62-6 methyl (2-methoxyphenoxy) ethanoate 
• 1400880-11-6 C₅₆H₄₄O₆P₂Ru 
• 1400880-13-8 C₄₉H₃₈O₄P₂Ru 
• 227300-29-0 2-(2-methoxyphenoxy)-1-phenylpropane-1,3-diol 
• 17078-88-5 1-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)ethanol 
• 22675-96-3 2-methoxyphenoxy-3',4'-dimethoxyacetophenone 

Relevant articles and documents

Cleavage∕cross-coupling strategy for converting β-O-4 linkage lignin model compounds into high valued benzyl amines via dual C–O bond cleavage

Lignin is the most recalcitrant of the three components of lignocellulosic biomass. The strength and stability of the linkages have long been a great challenge for the degradation and valorization of lignin biomass to obtain bio-fuels and commercial chemicals. Up to now, the selective cleavage of C–O linkages of lignin to afford chemicals contains only C, H and O atoms. Our group has developed a cleavage/cross-coupling strategy for converting 4-O-5 linkage lignin model compounds into high value-added compounds. Herein, we present a palladium-catalyzed cleavage/cross-coupling of the β-O-4 lignin model compounds with amines via dual C–O bond cleavage for the preparation of benzyl amine compounds and phenols.

Gold nanoparticles stabilized by graphene quantum dots as catalysts for C–C bond cleavage in β-O-4 lignin model compounds

In this work, we report oxidative cleavage of C–C bonds in β-O-4 lignin models that is catalyzed by gold nanoparticles stabilized by graphene quantum dots (AuNPs-GQDs). We demonstrate that GQDs can enhance the catalytic activity of AuNPs. The AuNPs-GQDs shows the highest catalytic activity when the mass ratio of AuNPs to GQDs is of 1:18. Moreover, AuNPs-GQDs exhibits higher activity in the cleavage of Cα–Cβ bond of the compounds when their Cβ is adjacent to an oxygen atom. The possible oxidation pathway is proposed.