99646-08-9

Basic information

• Product Name: c-2-(1-hydroxy-1-methylethyl)-2-methylcyclohexan-r-1-ol
• CAS NO: 99646-08-9
• Molecular Weight: 172.268
• Mol File: 99646-08-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: c-2-(1-hydroxy-1-methylethyl)-2-methylcyclohexan-r-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: c-2-(1-hydroxy-1-methylethyl)-2-methylcyclohexan-r-1-ol(99646-08-9)
• EPA Substance Registry System: c-2-(1-hydroxy-1-methylethyl)-2-methylcyclohexan-r-1-ol(99646-08-9)

Safety Data

• Hazardous Substances Data: 99646-08-9(Hazardous Substances Data)

Upstream product

• 99646-11-4 2-(1-hydroxy-1-methylethyl)-2-methylcyclohexanone 
• 7583-74-6 1,2-epoxy-1-t-butylcyclohexane 
• 186038-23-3 (1R,2R)-2-Hydroxy-1-methyl-cyclohexanecarbaldehyde 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 69551-50-4 trans-2-Hydroxymethyl-2-methyl-cyclohexanol 
• 66088-37-7 ethyl 1-methyl-2-oxocyclohexancarboxylate 

Downstream Products

• 99646-11-4 2-(1-hydroxy-1-methylethyl)-2-methylcyclohexanone 

Relevant articles and documents

Designed Chiral Acyl Radical Equivalents. Preparation and Cyclizations of Disymmetrically Substituted 1,3-Dioxabicyclo[4.4.0]decan-2-yl Radicals

The diastereoselectivity of 5-exo-trigonal cyclizations of 2-(4-penten-1-yl)-1,3-dioxolan-2-yl and 2-(4- penten-1-yl)-1,3-dioxan-2-yl radicals is investigated. When dioxolanes or dioxanes derived from C2 symmetrically substituted diols are employed the diastereoselectivity is poor. In the dioxanyl series this is a consequence of the cyclization occurring through a twist-boat conformer. Disymmetrically substituted dioxanyl radicals, derived from the alcohols 21 and 41, are, however, constrained to chairlike conformations and accordingly give rise to highly diastereoselective cyclizations. Conditions are described for the hydrolysis of the resulting spiroacetals and for determination of the ee of the resulting 2-methylcyclopentanones.