99683-26-8

Basic information

• Product Name: (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate
• Synonyms: (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate
• CAS NO: 99683-26-8
• Molecular Weight: 220.268
• Mol File: 99683-26-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate(99683-26-8)
• EPA Substance Registry System: (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate(99683-26-8)

Safety Data

• Hazardous Substances Data: 99683-26-8(Hazardous Substances Data)

Upstream product

• 19129-92-1 methyl 2-bromovalerate 
• 86895-69-4 methyl 2-phenylsulphinylpentanoate 
• 86895-65-0 α-phenylthio methyl pentanoate 
• 66716-61-8 methyl (Z)-2-phenylthiopent-2-enoate 
• 818-58-6 methyl (E)-pent-3-enoate 
• 100-52-7 benzaldehyde 
• 99683-11-1 (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate 

Relevant articles and documents

P(RNCH2CH2)3N-catalyzed 1,2-addition reactions of activated allylic synthons

Activated allylic compounds of the type RCH:CHCH2Z (Z = CN, CO2Me) react efficiently with aromatic aldehydes in the presence of 20-40 mol % of P(R′NCH2CH2)3N at -94 to -63 °C. Both R = H and R = Me le

Reactions of α-or χ-Phenylthio Substituted Extended Enolate Anions Derived from Esters

The title anions are alkylated and acylated (α series only) exclusively at the α position.The α-phenylthio products give χ-phenylthio compounds by the PhS shift and the PhS group may be removed from the products in a number of ways.