997-11-5Relevant articles and documents
Sokolov,Setkina
, (1969)
IMPORTANCE OF AMINE HYDROHALIDES IN ALCOHOLYSIS OF PHOSPHOROUS ACID AMIDES
Nifantyev, E. E.,Gratchev, M. L.,Borisov, M. L.,Bekker, A. R.
, p. 105 - 108 (2007/10/02)
The data are presented on the rates of deuteromethanolysis of 2-fluoro-1,3,2-dioxaphosphorinane 1 in the presence of various bases differing in the basicity and of that of 2-amino-1,3,2-dioxaphosphorinanes 22-4 catalysed by hydrogen fluoride salts of different amines.The alcoholysis of the fluorophosphite 1 in the presence of imidazole, N-ethylaniline and 2,6-di-tert-butyl-4-methylpiridine proceeds slowly whereas alcoholysis of the amidoesters 3,4 catalysed by imidazole and N-ethylaniline hydrofluorides occurs rapidly even at room temperature.These data do not match the hypothesis that halophosphites are intermediates in the alcoholysis of amidophosphites in the presence of amine hydrohalides.
NUCLEOPHILIC ADDITION TO COORDINATED ALLYL LIGANDS. HETEROATOM NUCLEOPHILES WITH CATIONIC MOLYBDENUM COMPLEXES
Vanarsdale, W. E.,Winter, R. E. K.,Kochi, J. K.
, p. 31 - 54 (2007/10/02)
The addition of the heteronuclear anions (methoxide, hydride, alkylnitronate and mercaptide) to a series of ?-allylmolybdenum cations, related to η5-C5H5Mo(CO)(NO)(η3-alyl)+ was examined.In each case, the adducts derived f