99773-42-9

Basic information

• Product Name: 2-Hydroxy-2-methyl-1-((2S,3S)-3-phenyl-oxiranyl)-propan-1-one
• CAS NO: 99773-42-9
• Molecular Weight: 206.241
• Mol File: 99773-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Hydroxy-2-methyl-1-((2S,3S)-3-phenyl-oxiranyl)-propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxy-2-methyl-1-((2S,3S)-3-phenyl-oxiranyl)-propan-1-one(99773-42-9)
• EPA Substance Registry System: 2-Hydroxy-2-methyl-1-((2S,3S)-3-phenyl-oxiranyl)-propan-1-one(99773-42-9)

Safety Data

• Hazardous Substances Data: 99773-42-9(Hazardous Substances Data)

Upstream product

• 115-22-0 3-Hydroxy-3-methyl-2-butanone 
• 99773-41-8 1-bromo-3-methyl-3-trimethylsilyloxy-butan-2-one 
• 55816-60-9 3-methyl-3-<(trimethylsilyl)oxy>-2-butanone 
• 99773-64-5 (1S,2R)-2-Bromo-1-hydroxy-4-methyl-1-phenyl-4-trimethylsilanyloxy-pentan-3-one 
• 100-52-7 benzaldehyde 
• 76777-60-1 5-Hydroxy-5-phenyl-2-<(trimethylsilyl)oxy>-2-methyl-3-pentanone 
• 63677-96-3 (E)-2-hydroxy-2-methyl-5-phenylpent-4-en-3-one 

Downstream Products

• 1566-68-3 (2RS,3SR)-2,3-epoxy-3-phenyl-propionic acid 
• 73610-79-4 (2SR,3SR)-3-phenyl-oxirane-2-carboxylic acid 
• 5693-99-2 cis-3-phenyloxirane-2-carboxaldehyde 
• 19190-80-8 cis-methyl 2,3-epoxy-3-phenylpropanoate 
• 19190-80-8 methyl trans-3-phenylglycidate 
• 5693-99-2 (±)-3-phenyloxirane-2-carbaldehyde 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXYESTERS AND ALDEHYDES VIA DIVALENT TIN ENOLATE. A SYNTHESIS OF 2-AMINO-2-DEOXY-D-ARABINITOL

A convenient method for the stereoselective synthesis of cis-α,β-epoxyesters and aldehydes is established according to the Sn(OTf)2 mediated cross aldol reaction between α-bromo-α'-silyloxyketone and aldehyde.The reaction is applied to the stereoselective synthesis of 2-amino-2-deoxy-D-arabinitol.